Behavior Analysis of Environmental Hydrogen in High-Magnesium Al-Mg Alloys by Hydrogen Microprint Technique

2007 ◽  
Vol 539-543 ◽  
pp. 475-480 ◽  
Author(s):  
T. Izumi ◽  
Goroh Itoh

High-magnesium Al-Mg alloys are known to be sensitive to stress corrosion cracking involving environmental hydrogen, hydrogen invading from the corrosive environment. In this study, the behavior of the environmental hydrogen in Al-6%Mg and Al-8%Mg binary alloy sheets stretched by 10% during exposure to 3.5%NaCl solution has been investigated by means of hydrogen microprint technique. Microprint image is observed on one surface while the other surface is exposed to the solution. In both alloys, the silver particles corresponding to the sites where hydrogen atoms are emitted from the inside of the sheets are shown on the slip lines. It is shown that the hydrogen atoms are transported with moving dislocations in the alloys.

CORROSION ◽  
10.5006/2317 ◽  
2017 ◽  
Vol 73 (4) ◽  
pp. 347-361 ◽  
Author(s):  
M.E. McMahon ◽  
P.J. Steiner ◽  
A.B. Lass ◽  
J.T. Burns

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Longkui Zhu ◽  
Yao Li

AbstractAs a significant cause of disastrous accidents, stress corrosion cracking (SCC) under elastic loads was investigated in type 316 L single-crystal stainless steel immersed in a boiling 45 wt% MgCl2 solution. Three-dimensional microcrack morphologies, characterized using synchrotron-based X-ray computed tomography, indicate that the SCC advanced along the cleavage planes (1 0 0) with the lowest free surface energy. The first-principles simulations show that synergistic adsorption of H and Cl atoms in the octahedral interstices minimized the surface energy of the cleavage planes (0 0 1) owing to a 73% reduction. Afterwards, the cleavage-dissolution mechanism is put forward, proposing that the SCC essentially originates from preferential brittle rupture of the corrosive environment particle adsorbed low-surface-energy cleavage planes in the elastic stress concentration zones, and anodic dissolution along the crack fronts. Besides, the corrosive environment particles primarily consist of the hydrogen atoms and the electronegative ions such as the chlorine ions.


CORROSION ◽  
10.5006/2343 ◽  
2017 ◽  
Vol 73 (6) ◽  
pp. 713-723 ◽  
Author(s):  
M.E. McMahon ◽  
P.J. Steiner ◽  
A.B. Lass ◽  
J.T. Burns

Sign in / Sign up

Export Citation Format

Share Document