pentacoordinate silicon
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Synthesis and Optical Resolution of Configurationally Stable Zwitterionic Pentacoordinate Silicon Derivatives

2021 ◽  
Author(s):  
Thomas Deis ◽  
Julien Maury ◽  
Fabrizio Medici ◽  
Marion Jean ◽  
Jérémy Forte ◽  
...  
Keyword(s):  
Optical Resolution ◽  
Pentacoordinate Silicon

Synthesis and Optical Resolution of Configurationally Stable Zwitterionic Pentacoordinate Silicon Derivatives

2021 ◽  
Author(s):  
Thomas Deis ◽  
Julien Maury ◽  
Fabrizio Medici ◽  
Marion Jean ◽  
Jérémy Forte ◽  
...  
Keyword(s):  
Optical Resolution ◽  
Pentacoordinate Silicon

Planar pentacoordinate silicon and germanium atoms

2020 ◽  
Vol 56 (89) ◽  
pp. 13772-13775 ◽  
Author(s):  
Meng-hui Wang ◽  
Xue Dong ◽  
Zhong-hua Cui ◽  
Mesías Orozco-Ic ◽  
Yi-hong Ding ◽  
...  
Keyword(s):  
Global Minimum ◽  
Group 14 ◽  
Pentacoordinate Silicon ◽  
Silicon And Germanium

The global minimum of XMg4Y− (X = Si, Ge; Y = In, Tl) and SiMg3In2 contains a planar pentacoordinate atom of group 14 other than carbon.

Pentacoordinate silicon compounds based on 2,2′-dihydroxyazobenzene ligand

2019 ◽  
Vol 903 ◽  
pp. 120997 ◽  
Author(s):  
Anastasiya S. Soldatenko ◽  
Irina V. Sterkhova ◽  
Nataliya F. Lazareva
Keyword(s):  
Silicon Compounds ◽  
Pentacoordinate Silicon

Mono- and bimetallic pentacoordinate silicon complexes of a chelating bis(catecholimine) ligand

2019 ◽  
Vol 48 (30) ◽  
pp. 11565-11574 ◽  
Author(s):  
Thomas H. Do ◽  
Seth N. Brown
Keyword(s):  
Pentacoordinate Silicon

A xanthenediamine-based bis(iminocatecholate) occupies trans sites in square pyramidal silicon adducts and binds univalent ions in a lower N2O3 pocket.

Tetrel bonds between PhSiF3 /PhTH3 (T = Si, Ge, Sn) and H3 ZO (Z = N, P, As): A pentacoordinate silicon (IV) complex

2018 ◽  
Vol 118 (17) ◽  
pp. e25660 ◽  
Author(s):  
Hui-Li Xu ◽  
Jian-Bo Cheng ◽  
Hai-Bei Li ◽  
Xin Yang ◽  
Qing-Zhong Li
Keyword(s):  
Pentacoordinate Silicon ◽  
Tetrel Bonds

Synthesis of Stable Pentacoordinate Silicon(IV)–NHC Adducts: An Entry to Anionic N-Heterocyclic Carbene Ligands

2018 ◽  
Vol 37 (4) ◽  
pp. 517-520 ◽  
Author(s):  
Fabrizio Medici ◽  
Geoffrey Gontard ◽  
Etienne Derat ◽  
Gilles Lemière ◽  
Louis Fensterbank
Keyword(s):  
Carbene Ligands ◽  
Pentacoordinate Silicon

A two-dimensional CaSi monolayer with quasi-planar pentacoordinate silicon

2018 ◽  
Vol 3 (3) ◽  
pp. 327-334 ◽  
Author(s):  
Yu Wang ◽  
Man Qiao ◽  
Yafei Li ◽  
Zhongfang Chen
Keyword(s):  
Two Dimensional ◽  
Pentacoordinate Silicon

In a CaSi monolayer, each Si atom binds with four calcium (Ca) atoms and one Si atom in almost the same plane to form a quasi ppSi moiety.

Synthesis of π-Conjugated Polymers Containing Dibenzosilepin Moieties with Pentacoordinate Silicon

2015 ◽  
Vol 88 (9) ◽  
pp. 1350-1355 ◽  
Author(s):  
Yuichiro Tokoro ◽  
Kazuo Tanaka ◽  
Yoshiki Chujo
Keyword(s):  
Conjugated Polymers ◽  
Pentacoordinate Silicon

Analysis of the Hypersensitivity of the 29Si NMR Chemical Shift of the Pentacoordinate Silicon Compounds to the Temperature Effect. N-(Silylmethyl)acetamides

2015 ◽  
Vol 119 (15) ◽  
pp. 3663-3673 ◽  
Author(s):  
Evgeniya P. Doronina ◽  
Valery F. Sidorkin ◽  
Nataliya F. Lazareva
Keyword(s):  
Chemical Shift ◽  
Temperature Effect ◽  
29Si Nmr ◽  
Nmr Chemical Shift ◽  
Silicon Compounds ◽  
Pentacoordinate Silicon
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