mechanistic probe
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2020 ◽  
Vol 26 (6) ◽  
pp. 1328-1334 ◽  
Author(s):  
Kristina V. Goncharenko ◽  
Sebastian Flückiger ◽  
Cangsong Liao ◽  
David Lim ◽  
Anja R. Stampfli ◽  
...  
Keyword(s):  

2019 ◽  
Author(s):  
David Lacy

The Marcus cross relation has been used for outer sphere electron transfer, proton transfer, hydride transfer, and proton-coupled electron transfer. This work shows that the same Marcus cross relation is useful in determining rate constants for inner sphere reduction of molecular oxygen. This has many implications in the field of small molecule activation in the form of catalyst design and as an indirect mechanistic probe.


2019 ◽  
Author(s):  
David Lacy

The Marcus cross relation has been used for outer sphere electron transfer, proton transfer, hydride transfer, and proton-coupled electron transfer. This work shows that the same Marcus cross relation is useful in determining rate constants for inner sphere reduction of molecular oxygen. This has many implications in the field of small molecule activation in the form of catalyst design and as an indirect mechanistic probe.


2019 ◽  
Author(s):  
David Lacy

The Marcus cross relation has been used for outer sphere electron transfer, proton transfer, hydride transfer, and proton-coupled electron transfer. This work shows that the same Marcus cross relation is useful in determining rate constants for inner sphere reduction of molecular oxygen. This has many implications in the field of small molecule activation in the form of catalyst design and as an indirect mechanistic probe.


2019 ◽  
Vol 38 (9) ◽  
pp. 2233-2238
Author(s):  
Gregory T. Whiteker ◽  
Fangzheng Li ◽  
Robert D. J. Froese ◽  
Michael L. Tulchinsky ◽  
Amaruka Hazari ◽  
...  

2019 ◽  
Author(s):  
David Lacy

The Marcus cross relation has been used for outer sphere electron transfer, proton transfer, hydride transfer, and proton-coupled electron transfer. This work shows that the same Marcus cross relation is useful in determining rate constants for inner sphere reduction of molecular oxygen. This has many implications in the field of small molecule activation in the form of catalyst design and as an indirect mechanistic probe.


2019 ◽  
Author(s):  
David Lacy

The Marcus cross relation has been used for outer sphere electron transfer, proton transfer, hydride transfer, and proton-coupled electron transfer. This work shows that the same Marcus cross relation is useful in determining rate constants for inner sphere reduction of molecular oxygen. This has many implications in the field of small molecule activation in the form of catalyst design and as an indirect mechanistic probe.


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