NMR Spectroscopic Study of Tautomerism in Solution and in the Solid State

Tautomerism ◽  
2013 ◽  
pp. 103-143 ◽  
Author(s):  
Erich Kleinpeter
Keyword(s):  
Solid State ◽  
Spectroscopic Study

Spectroscopic study of neodymium doped potassium lead bromide for mid-infrared solid state lasers

2013 ◽  
Vol 133 ◽  
pp. 244-248 ◽  
Author(s):  
E. Brown ◽  
C.B. Hanley ◽  
U. Hömmerich ◽  
A.G. Bluiett ◽  
S.B. Trivedi
Keyword(s):  
Solid State ◽  
Spectroscopic Study ◽  
Solid State Lasers ◽  
Mid Infrared ◽  
Lead Bromide

[Ag(PPh 3 ) 4 ][(PPh 3 )CdCl 3 ], the first monomeric trichlorocadmate complex bonded to a phosphorus ligand: A structural and spectroscopic study in solution and solid state

2016 ◽  
Vol 70 ◽  
pp. 35-40
Author(s):  
Emanuele Priola ◽  
Elisabetta Bonometti ◽  
Roberto Rabezzana ◽  
Roberto Buscaino ◽  
Michele R. Chierotti ◽  
...  
Keyword(s):  
Solid State ◽  
Spectroscopic Study

A 31P and 199Hg nuclear magnetic resonance and vibrational spectroscopic study of phosphine complexes of Hg(ClO4)2

1984 ◽  
Vol 62 (3) ◽  
pp. 621-627 ◽  
Author(s):  
Tim Allman ◽  
Ram G. Goel
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Magnetic Resonance ◽  
Spectroscopic Study ◽  
Vibrational Spectroscopy ◽  
Low Frequency ◽  
Sample Concentration ◽  
Phosphine Complexes ◽  
Nuclear Magnetic

Cationic complexes of the type [Hg(phosphine)n](ClO4)2 (n = 2, 3, 4) (phosphine = P(t-Bu)3, PCy3, P(4-Me2NC6H4)3, P(4-MeOC6H4)3, P(4-MeC6H4)3, P(3-MeC6H4)3, P(2-MeC6H4)3, P(4-FC6H4)3, P(4-ClC6H4)3) have been prepared and studied by vibrational spectroscopy in the perchlorate and low frequency regions, as well as by 31P and 199Hg nmr. The skeletal Hg—P frequencies have been assigned in both solution and the solid state. It was found that 1J(Hg—P) decreases with increasing phosphine basicity and that it is also dependent upon sample concentration and temperature.

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