A New Approach to Axially Chiral BipyridineN,N′-Dioxides Bearing Aromatic Substituents and their Use for Catalytic Asymmetric Allylation of Aldehydes with Allyl(trichloro)silane

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The first total synthesis of (+)-artalbic acid has been accomplished using asymmetric allylation of an acetoacetate derivative with a phase-transfer catalyst.


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