Two-in-One: Inherent Anhydrous and Water-Assisted High Proton Conduction in a 3D Metal-Organic Framework

2013 ◽  
Vol 126 (10) ◽  
pp. 2676-2680 ◽  
Author(s):  
Sanjog S. Nagarkar ◽  
Sreekuttan M. Unni ◽  
Amitosh Sharma ◽  
Sreekumar Kurungot ◽  
Sujit K. Ghosh
Keyword(s):  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton ◽  
Metal Organic ◽  
Organic Framework

High Proton Conduction at above 100 °C Mediated by Hydrogen Bonding in a Lanthanide Metal–Organic Framework

2014 ◽  
Vol 136 (35) ◽  
pp. 12444-12449 ◽  
Author(s):  
Qun Tang ◽  
Yiwei Liu ◽  
Shuxia Liu ◽  
Danfeng He ◽  
Jun Miao ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Organic Framework

scholarly journals Functionality in metal–organic framework minerals: proton conductivity, stability and potential for polymorphism

2019 ◽  
Vol 10 (18) ◽  
pp. 4923-4929 ◽  
Author(s):  
Igor Huskić ◽  
Novendra Novendra ◽  
Dae-Woon Lim ◽  
Filip Topić ◽  
Hatem M. Titi ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton ◽  
Metal Organic ◽  
Structure Retention ◽  
Organic Framework

Metal–organic framework minerals stepanovite and zhemchuzhnikovite can exhibit high proton conduction and structure retention on dehydration.

Straightforward Loading of Imidazole Molecules into Metal–Organic Framework for High Proton Conduction

2017 ◽  
Vol 139 (44) ◽  
pp. 15604-15607 ◽  
Author(s):  
Yingxiang Ye ◽  
Weigang Guo ◽  
Lihua Wang ◽  
Ziyin Li ◽  
Zhengju Song ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton ◽  
Metal Organic ◽  
Organic Framework

Two-in-One: Inherent Anhydrous and Water-Assisted High Proton Conduction in a 3D Metal-Organic Framework

2013 ◽  
Vol 53 (10) ◽  
pp. 2638-2642 ◽  
Author(s):  
Sanjog S. Nagarkar ◽  
Sreekuttan M. Unni ◽  
Amitosh Sharma ◽  
Sreekumar Kurungot ◽  
Sujit K. Ghosh
Keyword(s):  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton ◽  
Metal Organic ◽  
Organic Framework

High proton conduction in an excellent water-stable gadolinium metal–organic framework

2019 ◽  
Vol 55 (9) ◽  
pp. 1241-1244 ◽  
Author(s):  
Xiu-Shuang Xing ◽  
Zhi-Hua Fu ◽  
Ning-Ning Zhang ◽  
Xiao-Qing Yu ◽  
Ming-Sheng Wang ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
Proton Conducting ◽  
High Proton ◽  
Metal Organic ◽  
Organic Framework

Proton conductivity of a new gadolinium(iii) metal–organic framework, is among the highest values for proton-conducting MOFs.

A stable porphyrinic metal–organic framework pore-functionalized by high-density carboxylic groups for proton conduction

2017 ◽  
Vol 5 (28) ◽  
pp. 14525-14529 ◽  
Author(s):  
Hao Wu ◽  
Fan Yang ◽  
Xiu-Liang Lv ◽  
Bin Wang ◽  
Yong-Zheng Zhang ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Density ◽  
Carboxylic Group ◽  
High Proton Conductivity ◽  
High Proton ◽  
Carboxylic Groups ◽  
Metal Organic ◽  
Organic Framework

A highly stable porphyrinic MOF with free-carboxylic group functionalized pore surfaces exhibits a high proton conductivity of 3.9 × 10−2 S cm−1 at 80 °C and 97% RH, which is comparable to most of the reported proton conductive MOFs.

Iron(iii) identification and proton conduction of a luminescent cadmium–organic framework

2018 ◽  
Vol 42 (24) ◽  
pp. 20197-20204 ◽  
Author(s):  
Xiaoxin Xie ◽  
Shihang Yu ◽  
Chenglin Yang ◽  
Jian Zhang ◽  
Zifeng Li ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Recognition Performance ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
Recognition Mechanism ◽  
High Proton ◽  
Metal Organic ◽  
Organic Framework

A luminescent metal–organic framework, [Cd(HDMPhIDC)(H2O)]n (1), has been successfully synthesized and structurally characterized. MOF 1 exhibits good recognition performance for Fe3+ ions. The recognition mechanism of Fe3+ was explored by UV-Vis and PXRD determinations. 1 was found to have a high proton conductivity value of 1.30 × 10−4 S cm−1 at 100 °C and 98% RH.

scholarly journals Theoretical hydrogen bonding calculations and proton conduction for Eu(iii)-based metal–organic framework

RSC Advances ◽  
2021 ◽  
Vol 11 (19) ◽  
pp. 11495-11499
Author(s):  
Lu Feng ◽  
Tian-Yu Zeng ◽  
Hao-Bo Hou ◽  
Hong Zhou ◽  
Jian Tian
Keyword(s):  
Hydrogen Bonding ◽  
Theoretical Calculation ◽  
Proton Transport ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
Transport Channel ◽  
Proton Conducting ◽  
Metal Organic ◽  
Organic Framework

A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation.

scholarly journals Facile Proton Conduction via Ordered Water Molecules in a Phosphonate Metal−Organic Framework

2010 ◽  
Vol 132 (40) ◽  
pp. 14055-14057 ◽  
Author(s):  
Jared M. Taylor ◽  
Roger K. Mah ◽  
Igor L. Moudrakovski ◽  
Christopher I. Ratcliffe ◽  
Ramanathan Vaidhyanathan ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Proton Conduction ◽  
Water Molecules ◽  
Metal Organic ◽  
Ordered Water ◽  
Organic Framework
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