scholarly journals Cover Picture: Efficient Trapping of Trace Acetylene from Ethylene in an Ultramicroporous Metal–Organic Framework: Synergistic Effect of High‐Density Open Metal and Electronegative Sites (Angew. Chem. Int. Ed. 43/2020)

2020 ◽  
Vol 59 (43) ◽  
pp. 18821-18821
Author(s):  
Zhaoqiang Zhang ◽  
Shing Bo Peh ◽  
Yuxiang Wang ◽  
Chengjun Kang ◽  
Weidong Fan ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Metal Organic Framework ◽  
High Density ◽  
Metal Organic ◽  
Organic Framework

Efficient Trapping of Trace Acetylene from Ethylene in an Ultramicroporous Metal–Organic Framework: Synergistic Effect of High‐Density Open Metal and Electronegative Sites

2020 ◽  
Vol 132 (43) ◽  
pp. 19089-19094
Author(s):  
Zhaoqiang Zhang ◽  
Shing Bo Peh ◽  
Yuxiang Wang ◽  
Chengjun Kang ◽  
Weidong Fan ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Metal Organic Framework ◽  
High Density ◽  
Metal Organic ◽  
Organic Framework

A metal–organic framework with in situ generated low-coordinate binuclear Cu(i) units as a highly effective catalyst for photodriven hydrogen production

2020 ◽  
Vol 56 (49) ◽  
pp. 6700-6703
Author(s):  
Ning-Yu Huang ◽  
Hai He ◽  
Hao Li ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Production ◽  
Synergistic Effect ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Binuclear Copper ◽  
Metal Organic ◽  
Cu Ions ◽  
Organic Framework

Here, we report a metal–organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g−1 h−1) for photodriven H2 generation, which is attributed to the synergistic effect between the two Cu ions.

Precise regulating synergistic effect in metal–organic framework for stepwise-controlled adsorption

2021 ◽  
Author(s):  
Jiaxing Zhu ◽  
Yi Yu ◽  
Hongchuan Fan ◽  
Huaqiang Cai ◽  
Zhenxia Chen ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Shape Change ◽  
Metal Organic Framework ◽  
Pore Shape ◽  
Metal Organic ◽  
Controlled Adsorption ◽  
Dyes Mixture ◽  
Organic Framework

MAC-20 shows a unique two-step pore-shape change and executes a stepwise-controlled adsorption of dyes mixture in order of their sizes.

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