Synthesis of Indanones and Spiroindanones by Diastereoselective Annulation Based on a Hydrogen Autotransfer Strategy

Ruthenium(II) Complexes with N-Heterocyclic Carbene-Phosphine Ligands for the N-Alkylation of Amines with Alcohols

Organic & Biomolecular Chemistry ◽

10.1039/d1ob00362c ◽

2021 ◽

Author(s):

Ming Huang ◽

Yinwu Li ◽

Xiao-Bing Lan ◽

Jiahao Liu ◽

Cunyuan Zhao ◽

...

Keyword(s):

Metal Hydride ◽

Phosphine Ligands ◽

Hydride Complexes ◽

Borrowing Hydrogen ◽

Hydrogen Autotransfer

Metal hydride complexes are key intermediates for N-alkylation of amines with alcohols by borrowing hydrogen/hydrogen autotransfer (BH/HA) strategy. Reactivity tuning of metal hydride complexes could adjust the dehydrogenation of alcohols...

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ChemInform Abstract: N-Alkylation of Poor Nucleophilic Amines and Derivatives with Alcohols by a Hydrogen Autotransfer Process Catalyzed by Copper(II) Acetate: Scope and Mechanistic Considerations.

ChemInform ◽

10.1002/chin.201133033 ◽

2011 ◽

Vol 42 (33) ◽

pp. no-no

Author(s):

Ana Martinez-Asencio ◽

Diego J. Ramon ◽

Miguel Yus

Keyword(s):

Hydrogen Autotransfer

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Iridium Complex-Catalyzed C2-Extension of Primary Alcohols with Ethanol via a Hydrogen Autotransfer Reaction

The Journal of Organic Chemistry ◽

10.1021/acs.joc.0c01540 ◽

2020 ◽

Vol 85 (18) ◽

pp. 11952-11958

Author(s):

Masaki Kobayashi ◽

Satoshi Itoh ◽

Keisuke Yoshimura ◽

Yuya Tsukamoto ◽

Yasushi Obora

Keyword(s):

Iridium Complex ◽

Primary Alcohols ◽

Hydrogen Autotransfer

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Hydrogen Autotransfer in theN-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles

Chemical Reviews ◽

10.1021/cr9002159 ◽

2009 ◽

Vol 110 (3) ◽

pp. 1611-1641 ◽

Cited By ~ 851

Author(s):

Gabriela Guillena ◽

Diego J. Ramón ◽

Miguel Yus

Keyword(s):

Hydrogen Autotransfer ◽

Related Compounds

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Reinvestigating Raney nickel mediated selective alkylation of amines with alcohols via hydrogen autotransfer methodology

Applied Catalysis A General ◽

10.1016/j.apcata.2014.04.009 ◽

2014 ◽

Vol 478 ◽

pp. 241-251 ◽

Cited By ~ 28

Author(s):

Astha Mehta ◽

A. Thaker ◽

V. Londhe ◽

Santosh R. Nandan

Keyword(s):

Raney Nickel ◽

Hydrogen Autotransfer ◽

Selective Alkylation

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N-Alkylation of poor nucleophilic amine and sulfonamide derivatives with alcohols by a hydrogen autotransfer process catalyzed by copper(II) acetate

Tetrahedron Letters ◽

10.1016/j.tetlet.2009.11.009 ◽

2010 ◽

Vol 51 (2) ◽

pp. 325-327 ◽

Cited By ~ 78

Author(s):

Ana Martínez-Asencio ◽

Diego J. Ramón ◽

Miguel Yus

Keyword(s):

Hydrogen Autotransfer

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N-Alkylation by Hydrogen Autotransfer Reactions

Topics in Current Chemistry ◽

10.1007/s41061-016-0027-1 ◽

2016 ◽

Vol 374 (3) ◽

Cited By ~ 30

Author(s):

Xiantao Ma ◽

Chenliang Su ◽

Qing Xu

Keyword(s):

Hydrogen Autotransfer

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Mechanistic study on the Cp*iridium-catalyzed N-alkylation of amines with alcohols

RSC Advances ◽

10.1039/c5ra02052b ◽

2015 ◽

Vol 5 (29) ◽

pp. 22996-23008 ◽

Cited By ~ 13

Author(s):

Guo-Ming Zhao ◽

Hui-ling Liu ◽

Xu-ri Huang ◽

Dan-dan Zhang ◽

Xue Yang

Keyword(s):

Mechanistic Study ◽

Dft Methods ◽

Hydrogen Autotransfer

Using DFT methods and the energetic span model, the most favorable hydrogen autotransfer pathway for the [Cp*IrCl2]2/K2CO3-catalyzed N-alkylation of amines with alcohols has been found.

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