Assessment of melamine in different water samples with ZnO‐doped Co3O4 nanoparticles fabricated glassy carbon electrode by differential pulse voltammetry

2021 ◽  
Author(s):  
Mohammed M. Rahman ◽  
M. M. Alam ◽  
Abdullah M. Asiri ◽  
Jamal Uddin
Keyword(s):  
Differential Pulse Voltammetry ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Water Samples ◽  
Differential Pulse ◽  
Co3o4 Nanoparticles ◽  
Carbon Electrode ◽  
Pulse Voltammetry

Determination of Drimarene Blue X-BLN at a glassy carbon electrode by differential pulse voltammetry

2011 ◽  
Vol 76 (12) ◽  
pp. 1765-1773 ◽  
Author(s):  
Abd-Elgawad M. Radi ◽  
Mohammed R. Mostafa ◽  
Reda M. Elshafey ◽  
Talaat A. Hegazy
Keyword(s):  
Differential Pulse Voltammetry ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Supporting Electrolyte ◽  
Differential Pulse ◽  
Redox Couple ◽  
Carbon Electrode ◽  
Validation Parameters ◽  
Pulse Voltammetry

The electrochemical oxidation behaviour of Drimarene Blue X-BLN (DB) has been investigated in phosphate buffers (pH 2.54–10.18) by cyclic and differential pulse voltammetry (DPV) at a glassy carbon electrode (GCE). The oxidation of DB dye generated well-defined pH-dependent two pairs of quasi-reversible anodic-cathodic peak couples. DB exhibited the second redox couple over the entire pH range, while the first redox couple disappeared for pH ≥ 6.70. The redox processes were adsorption-controlled. An electroanalytical method was developed for the determination of DB in phosphate buffer solution (pH 2.85) as supporting electrolyte using DPV. The anodic current heights varied linearly with DB concentrations in the ranges 2 × 10–6–3 × 10–5 and 6 × 10–6–3 × 10–5 mol l–1 with limits of detection (LOD) of 8.7 × 10–7 and 5.7 × 10–7 mol l–1 and limits of quantification (LOQ) of 2.9 × 10–6 and 1.9 × 10–6 mol l–1 for the first and second anodic peaks, respectively. Validation parameters, such as accuracy, precision and recovery were evaluated. The proposed method was successfully applied to the determination of DB in tap water and the analytical results compared well with those obtained by the spectrophotometric method.

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