Determination of Cadmium(II) by Differential Pulse Voltammetry (DPV) Using a Cerium(IV) Oxide: Polyaniline Composite Modified Glassy Carbon Electrode (GCE)

2021 ◽  
pp. 1-21
Author(s):  
Melis Altundal ◽  
Ahmet Üğe ◽  
Özer Gök ◽  
Bülent Zeybek
Keyword(s):  
Differential Pulse Voltammetry ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Differential Pulse ◽  
Carbon Electrode ◽  
Modified Glassy Carbon Electrode ◽  
Pulse Voltammetry

Voltammetric Determination of Guaifenesin in Pharmaceuticals and Urine Samples Based on Poly(Bromocresol Purple) Modified Glassy Carbon Electrode

2020 ◽  
Vol 16 (5) ◽  
pp. 633-639
Author(s):  
Fatma Ağın
Keyword(s):  
Differential Pulse Voltammetry ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Differential Pulse ◽  
Urine Samples ◽  
Bromocresol Purple ◽  
Carbon Electrode ◽  
Modified Glassy Carbon Electrode ◽  
Pulse Voltammetry

Introduction: The electro-oxidation behavior of expectorant drug Guaifenesin (GUF) was studied on poly(bromocresol purple) modified Glassy Carbon Electrode (GCE) by Cyclic Voltammetry (CV) and Differential Pulse Voltammetry (DPV) methods. Materials and Methods: GCE was modified with electropolymerization of Bromocresol Purple (BP) monomer for sensitive determination of GUF with voltammetric methods. The oxidation process of GUF showed irreversible and diffusion controlled behavior. The linearity has been obtained in the range from 1.00 × 10-7 to 2.00 × 10-5 M with the limit of detection 3.658 × 10-9 M for DPV in 0.1 M phosphate buffer solution (PBS) at pH 3.0. Results and Conclusion: Fully validated differential pulse voltammetry was successfully applied for the determination of GUF in pharmaceutical dosage forms and urine samples obtained satisfying results.

Determination of Drimarene Blue X-BLN at a glassy carbon electrode by differential pulse voltammetry

2011 ◽  
Vol 76 (12) ◽  
pp. 1765-1773 ◽  
Author(s):  
Abd-Elgawad M. Radi ◽  
Mohammed R. Mostafa ◽  
Reda M. Elshafey ◽  
Talaat A. Hegazy
Keyword(s):  
Differential Pulse Voltammetry ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Supporting Electrolyte ◽  
Differential Pulse ◽  
Redox Couple ◽  
Carbon Electrode ◽  
Validation Parameters ◽  
Pulse Voltammetry

The electrochemical oxidation behaviour of Drimarene Blue X-BLN (DB) has been investigated in phosphate buffers (pH 2.54–10.18) by cyclic and differential pulse voltammetry (DPV) at a glassy carbon electrode (GCE). The oxidation of DB dye generated well-defined pH-dependent two pairs of quasi-reversible anodic-cathodic peak couples. DB exhibited the second redox couple over the entire pH range, while the first redox couple disappeared for pH ≥ 6.70. The redox processes were adsorption-controlled. An electroanalytical method was developed for the determination of DB in phosphate buffer solution (pH 2.85) as supporting electrolyte using DPV. The anodic current heights varied linearly with DB concentrations in the ranges 2 × 10–6–3 × 10–5 and 6 × 10–6–3 × 10–5 mol l–1 with limits of detection (LOD) of 8.7 × 10–7 and 5.7 × 10–7 mol l–1 and limits of quantification (LOQ) of 2.9 × 10–6 and 1.9 × 10–6 mol l–1 for the first and second anodic peaks, respectively. Validation parameters, such as accuracy, precision and recovery were evaluated. The proposed method was successfully applied to the determination of DB in tap water and the analytical results compared well with those obtained by the spectrophotometric method.

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