Calculation of Vapor-Liquid Equilibrium Data of Binary Mixtures Using Vapor Pressure Data

2010 ◽  
Vol 33 (12) ◽  
pp. 2089-2094 ◽  
Author(s):  
T. Knorr ◽  
E. Aust ◽  
K.-H. Jacob
2014 ◽  
Vol 59 (5) ◽  
pp. 1643-1650 ◽  
Author(s):  
Ranjeetha Hirawan ◽  
Sumit Sinha ◽  
Samuel A. Iwarere ◽  
J. David Raal ◽  
Paramespri Naidoo ◽  
...  

2020 ◽  
Vol 840 ◽  
pp. 501-506
Author(s):  
Ardika Nurmawati ◽  
Rizky Tetrisyanda ◽  
Gede Wibawa

The addition of alcohol as an oxygenated compound in gasoline blends may increase the vapor pressure of gasoline mixture. As a result, the study of vapor-liquid equilibrium for gasoline component and alcohol is necessary. In this study, the vapor-liquid equilibrium of isobutanol – isooctane/n-heptane blends were obtained experimentally at temperatures in the range 303.15 to 323.15 K using modified simple quasi-static ebulliometer. The apparatus was validated by comparing the vapor pressure of pure isobutanol, isooctane, and n-heptane with the published data and giving average absolute deviation (AAD) between experimental and calculated ones with magnitude less than 1.0%. The addition of isobutanol with the mole fraction range from 0.2 to 0.6 would increase the vapor pressure of the isooctane and n-heptane up to 12% and 14% respectively. The vapor pressure of binary mixtures was correlated with the Wilson, Non-random two-liquid (NRTL), and Universal quasi-chemical (UNIQUAC) equations with AAD 1.6%, 1.5%, and 1.7%, respectively for isobutanol + isooctane system and 1.8%, 1.7%, and 2.0%, respectively for isobutanol + n-heptane system. The systems studied show positive deviation from Raoult’s Law.


2003 ◽  
Vol 48 (1) ◽  
pp. 44-47 ◽  
Author(s):  
Shubham P. Chopade ◽  
Atul D. Dhale ◽  
Angela M. Clark ◽  
Chris W. Kiesling ◽  
Laurie K. Myrant ◽  
...  

2018 ◽  
Vol 63 (5) ◽  
pp. 1228-1233 ◽  
Author(s):  
Deresh Ramjugernath ◽  
Alain Valtz ◽  
Dominique Richon ◽  
Mark D. Williams-Wynn ◽  
Christophe Coquelet

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