scholarly journals Supramolecular Coordination Cages Based on N‐Heterocyclic Carbene‐Gold(I) Ligands and Their Precursors: Self‐Assembly, Structural Transformation and Guest‐Binding Properties

2021 ◽  
Author(s):  
Wen‐Jie Shi ◽  
Dan Liu ◽  
Xin Li ◽  
Sha Bai ◽  
Yao‐Yu Wang ◽  
...  
Keyword(s):  
Structural Transformation ◽  
Self Assembly ◽  
Binding Properties ◽  
Guest Binding ◽  
Supramolecular Coordination ◽  
Coordination Cages

scholarly journals Geometric isomerism in coordination cages based on tris-chelate vertices: a tool to control both assembly and host/guest chemistry

2016 ◽  
Vol 45 (41) ◽  
pp. 16096-16111 ◽  
Author(s):  
Alexander J. Metherell ◽  
Michael D. Ward
Keyword(s):  
Binding Properties ◽  
Geometric Isomerism ◽  
Guest Binding ◽  
Coordination Cages ◽  
Guest Chemistry

The presence of both fac and mer tris-chelate units as coordination cage vertices allows control of both cage assembly and guest binding properties.

scholarly journals Xanthene[n]arenes: Exceptionally Large, Bowl-shaped Macrocyclic Building Blocks Suitable for Self-Assembly

2021 ◽  
Author(s):  
Jonathan Pfeuffer-Rooschüz ◽  
Alessandro Prescimone ◽  
Konrad Tiefenbacher
Keyword(s):  
Self Assembly ◽  
Building Blocks ◽  
The Novel ◽  
Supramolecular Systems ◽  
Binding Properties ◽  
Molecular Capsules ◽  
New Class ◽  
Guest Binding ◽  
Non Covalent Interactions ◽  
Covalent Interactions

<div>A new class of macrocycles denoted as “xanthene[n]arenes” was synthesized. In contrast to most other macrocycles, they feature a rigid bowl-shape, required for the synthesis of cavitands and for the self-assembly to molecular capsules via non-covalent interactions. The derivatization potential of the novel macrocycles was demonstrated on the xanthene[3]arene scaffold. Beside a deep cavitand, a modified macrocycle was synthesized that self-assembles into a hydrogen-bonded tetrameric capsule. Both supramolecular systems display host-guest binding properties, demonstrating the potential of xanthene[n]arenes as a new set of macrocyclic building blocks.</div>

Subcomponent Self-Assembly and Guest-Binding Properties of Face-Capped Fe4L48+ Capsules

2011 ◽  
Vol 134 (11) ◽  
pp. 5110-5119 ◽  
Author(s):  
Rana A. Bilbeisi ◽  
Jack K. Clegg ◽  
Noémie Elgrishi ◽  
Xavier de Hatten ◽  
Marc Devillard ◽  
...  
Keyword(s):  
Self Assembly ◽  
Binding Properties ◽  
Guest Binding

scholarly journals Xanthene[n]arenes: Exceptionally Large, Bowl-shaped Macrocyclic Building Blocks Suitable for Self-Assembly

2021 ◽  
Author(s):  
Jonathan Pfeuffer-Rooschüz ◽  
Alessandro Prescimone ◽  
Konrad Tiefenbacher
Keyword(s):  
Self Assembly ◽  
Building Blocks ◽  
The Novel ◽  
Supramolecular Systems ◽  
Binding Properties ◽  
Molecular Capsules ◽  
New Class ◽  
Guest Binding ◽  
Non Covalent Interactions ◽  
Covalent Interactions

<div>A new class of macrocycles denoted as “xanthene[n]arenes” was synthesized. In contrast to most other macrocycles, they feature a rigid bowl-shape, required for the synthesis of cavitands and for the self-assembly to molecular capsules via non-covalent interactions. The derivatization potential of the novel macrocycles was demonstrated on the xanthene[3]arene scaffold. Beside a deep cavitand, a modified macrocycle was synthesized that self-assembles into a hydrogen-bonded tetrameric capsule. Both supramolecular systems display host-guest binding properties, demonstrating the potential of xanthene[n]arenes as a new set of macrocyclic building blocks.</div>

Steric Control of Sorting Regimes in Self-Assembled Cages

2021 ◽  
Author(s):  
Samuel Edward Walker ◽  
Stephanie A Boer ◽  
Thomas Malcomson ◽  
Martin J. Paterson ◽  
Kellie Tuck ◽  
...  
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Steric Interactions ◽  
Coordination Cages ◽  
Self Assembled ◽  
Steric Control

Control of self-sorting regimes is achieved through adjustment of steric interactions in self-assembled coordination cages. The self-assembly regime of dynamic mixtures of heteroleptic cages is followed by HPLC to show...

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