ChemInform Abstract: SOLUBILIZATIN OF BENZENE IN AQUEOUS SOLUTIONS OF N-ALKYLAMMONIUM BROMIDE, N-ALKANOLS, ACETIC ACID AND PERCHLORIC ACID MEASURED BY DIFFERENTIAL SPECTROSCOPY

1973 ◽  
Vol 4 (37) ◽  
Author(s):  
SELWYN J. REHFELD
Keyword(s):  
Acetic Acid ◽  
Aqueous Solutions ◽  
Perchloric Acid ◽  
Differential Spectroscopy

Valorization of a natural residue (sawdust) as adsorbent to remove the acetic acid in aqueous solutions

2015 ◽  
Vol 56 (10) ◽  
pp. 2731-2738 ◽  
Author(s):  
Kamel Rida ◽  
Atika Bouanika ◽  
Meriem Boudellal ◽  
Ali Boukhemkhem
Keyword(s):  
Acetic Acid ◽  
Aqueous Solutions

scholarly journals Synthesis of Mn(II)-containing paratungstate B from aqueous solutions acidified by acetic acid

2021 ◽  
pp. 39-48
Keyword(s):  
Thermal Analysis ◽  
Acetic Acid ◽  
Aqueous Solutions ◽  
Equilibrium Constants ◽  
Background Electrolyte ◽  
Equilibrium Processes ◽  
Transformation Processes ◽  
Paratungstate B ◽  
Solution Acidity ◽  
Tungstate Anion

The method of pH-potentiometric titration and mathematical simulation were used to study the equilibrium processes in aqueous solutions of the WO42––CH3COOH–H2O system in the acidity range Z=(CH3COOH)/(Na2WO4)=0.8–1.7 at СW=0.01 mol L–1 and T=2980.1 K, a constant ionic strength being maintained by sodium nitrate as a background electrolyte ((NaNO3)=0.10 mol L–1). We developed the models of polyoxotungstate anions formation and the equilibrium transformation processes, which adequately describe experimental pH vs. Z dependences. It was found that acetic acid using to create the solution acidity that is necessary for the formation of isopoly tungstate anion contributes only to the formation of protonated paratungstate B anions Нх[W12O40(ОН)2](10–х)– (where x=0–4). We calculated the logarithms of the concentration equilibrium constants of the polyanion formation and plotted the distribution diagrams. Double sodium-manganese(II) paratungstate B Na8(H2O)28Mn(H2O)2[H2W12O42]4H2O was synthesized at Z=1.00 to confirm the results of the mathematical modeling. The chemical composition of the prepared salt was established by chemical elemental analysis, thermal analysis, FTIR spectroscopy, and single crystal X-ray analysis. The stepwise process of salt dehydration was studied by means of differential thermal analysis.

scholarly journals Kinetic Evidence of a Common Mechanism in the Oxidation by Chromium(vi) Complexes: Oxidation of Benzyl Alcohol

2000 ◽  
Vol 2000 (3) ◽  
pp. 114-115 ◽  
Author(s):  
Chockalingam Karunakaran ◽  
Sadasivam Suresh
Keyword(s):  
Acetic Acid ◽  
Benzyl Alcohol ◽  
Perchloric Acid ◽  
Mineral Acid ◽  
Common Mechanism ◽  
Aqueous Acetic Acid ◽  
First Order ◽  
Chromium Vi ◽  
Oxidation Of Benzyl Alcohol

The oxidation of benzyl alcohol by dichromate and seven chromium(VI) complexes in aqueous acetic acid in the presence of perchloric acid is first order each in the oxidants, the alcohol and the mineral acid. The oxidation conforms to the isokinetic and Exner relationships and follows a common mechanism.

Absorption of Herbicides by Soybean Seeds and Their Influence on Emergence and Seedling Growth

Weed Science ◽  
1972 ◽  
Vol 20 (5) ◽  
pp. 506-510 ◽  
Author(s):  
R. E. Phillips ◽  
D. B. Egli ◽  
L. Thompson
Keyword(s):  
Acetic Acid ◽  
Aqueous Solutions ◽  
Potassium Salt ◽  
Soybean Seeds ◽  
Experimental Procedure ◽  
Low Concentrations ◽  
High Concentrations ◽  
Shoot Weight ◽  
Total Oil ◽  
Dichlorophenoxy Acetic Acid

The total quantity and concentration of six herbicides, isopropylm-chlorocarbanilate (chlorpropham), 2-chloro-4-(ethylamino)-6-(isopropylamino-s-triazine (atrazine), 3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea (linuron), 2-chloro-2′,6′-diethyl-N-(methoxymethyl)acetanilide (alachlor), 3-amino-2,5-dichlorobenzoic acid (chloramben), and (2,4-dichlorophenoxy)acetic acid (2,4-D), in unaerated, aqueous solutions absorbed by seeds of 11 soybean(Glycine max(L.) Merr.) strains were measured. Mechanism of movement of the herbicides from the aqueous solutions to the seeds in the experimental procedure employed was diffusion. Total quantity and concentration of herbicide found in the seeds differed significantly for both herbicides and soybean strains. Total quantity of herbicide absorbed was determined by total oil and percent oil of the seeds. The capacity of the seeds to absorb a given herbicide was more closely related to percent oil of the seeds than to total oil of the seeds. The emergence and seedling shoot weight of ‘Cutler’ soybeans were not affected appreciably by concentrations of linuron, atrazine, and chloramben (potassium salt) but were reduced by high concentrations of chlorpropham and alachlor and relatively low concentrations of 2,4-D (potassium salt) in the seeds.

Sign in / Sign up

Export Citation Format

Share Document