ChemInform Abstract: X-RAY CRYSTAL STRUCTURE CHARACTERIZATION OF CYCLO(HEXACYANOBORANE), (BH2CN)6

A new bi-capped Keggin heteropoly molybdovanadated derivative, [Co (en)3]2[SiMo8V6O42]∙6H2O (1) (en = ethylendiamine) has been hydrothermally synthesized and structurally characterized by the elemental analysis, IR, XPS and single crystal X-ray diffraction. The crystal structure analysis reveals that compound 1 consists of [Co (en)3]2+transition metal coordination fragment and the [SiMo8V6O42]4-building blocks, which are linked together via hydrogen-bonding interactions to form a new 3-D supramolecular networks.

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SYNTHESIS, CRYSTAL STRUCTURE, HIRSHFELD SURFACE ANALYSIS AND QUANTUM CHEMICAL CALCULATIONS OF [Cu2(C6H9N3S)2(ClO4)2] π-COMPLEX WITH 2-ALLYLAMINO-5-METHYL-1,3,4-THIADIAZOLE

Odesa National University Herald Chemistry ◽

10.18524/2304-0947.2021.1(77).226133 ◽

2021 ◽

Vol 26 (1(77)) ◽

pp. 16-25

Author(s):

Yu. I. Slyvka ◽

E. A. Goreshnik ◽

N. T. Pokhodylo ◽

М. G. Mys’kiv

Keyword(s):

Crystal Structure ◽

Computational Analysis ◽

Structure Characterization ◽

Electrochemical Technique ◽

The Novel ◽

X Ray Diffraction ◽

X Ray ◽

Π Complex ◽

Centrosymmetric Dimers

This work is focused on the synthesis and structure characterization of the novel Cu(I) π-complex [Cu2(Thiaz1)2(ClO4)2] (1) with 2-allylamino-5-methyl-1,3,4-thiadiazole (Thiaz1) ligand. The crystals of the compound were obtained by means of the alternating-current electrochemical technique and studied using single crystal X-ray diffraction. The crystal structure of the complex 1 is constructed from the centrosymmetric dimers, in which two copper(I) ions are coordinated by two Thiaz1 molecules through thiadiazole N atoms and allylic C=C bond. Energy framework computational analysis for structure 1 has been performed.

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Synthesis, Isolation and X-ray Crystal Structure Characterization of Trans-γ-{(C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(diisothiocyanato)} Nickel(II) Complex

Journal of Chemical Crystallography ◽

10.1007/s10870-008-9393-z ◽

2008 ◽

Vol 38 (10) ◽

pp. 801-806 ◽

Cited By ~ 2

Author(s):

Tarun Kumar Misra ◽

Jack Cheng ◽

Tian-Huey Lu ◽

Fen-Ling Liao ◽

Chung-Sun Chung

Keyword(s):

Crystal Structure ◽

Structure Characterization ◽

X Ray

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Synthesis and Crystal Structure Characterization of Zinc (II) Tetronic Acid Complexes

Bioinorganic Chemistry and Applications ◽

10.1155/2010/651652 ◽

2010 ◽

Vol 2010 ◽

pp. 1-7 ◽

Cited By ~ 1

Author(s):

K. C. Prousis ◽

G. Athanasellis ◽

V. Stefanou ◽

D. Matiadis ◽

E. Kokalari ◽

...

Keyword(s):

Crystal Structure ◽

Hydrogen Bonding ◽

Structure Characterization ◽

Synthesis And Characterization ◽

Zinc Ions ◽

Carbonyl Groups ◽

Synthesis And Crystal Structure ◽

X Ray ◽

Tetronic Acid

The synthesis and characterization of two new tetronic acid zinc (II) complexes of the empirical formulae [Zn(L–H)2(H2O)2] (1) and [Zn(L–H)2(H2O)(MeOH)]H2O(2) found within the same crystal are reported. The zinc ions bind through alkoxide and carbonyl groups of the ligand 3-methoxycarbonyl-5-phenyl tetronic acid (LH) as indicated byHNMR and X-ray crystallographic studies. These complexes promote intra- and intermolecular interactions, such as hydrogen bonding andπstacking, giving place to the formation of molecular aggregates.

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ChemInform Abstract: Synthesis and X-Ray Crystal Structure Characterization of Zn2(HPO4)3. times.H3NCH2CH2NH3.

ChemInform ◽

10.1002/chin.199439029 ◽

2010 ◽

Vol 25 (39) ◽

pp. no-no

Author(s):

T. SONG ◽

J. XU ◽

Y. ZHAO ◽

Y. YUE ◽

Y. XU ◽

...

Keyword(s):

Crystal Structure ◽

Structure Characterization ◽

X Ray

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Crystal Structure Characterization of 4,4-diaminodiphenyl Sulfoxide

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.848.195 ◽

2013 ◽

Vol 848 ◽

pp. 195-198

Author(s):

Zhi Xiang Ji

Keyword(s):

Crystal Structure ◽

Three Dimensional ◽

Ethanol Solution ◽

Structure Characterization ◽

Monoclinic Space Group ◽

Crystal Data ◽

Single Crystal Diffraction ◽

X Ray ◽

Dimensional Network

The crystals of 4,4-diaminodiphenyl sulfoxide have been obtained by evaporation from ethanol solution. The crystal structure of the 4,4-diaminodiphenyl sulfoxide was determined by X-ray single crystal diffraction analysis. The crystal data for 4,4-diaminodiphenyl sulfoxide: monoclinic, space groupP2(1)/c,a= 49.068(10) Å,b= 11.439(2) Å,c= 13.103(3) Å,V= 7347(3) Å3,Z= 24,Mr= 248.30,De= 1.347 g/cm3,T= 298(2) K,F(000) = 3120,R= 0.0786 andwR =0.2653. The compound forms three-dimensional network structure through hydrogen bonds and π-π interaction.

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