ChemInform Abstract: THE REACTIVE BEHAVIOR OF 2-PYRIDYL SUBSTITUTED CARBODIIMIDES- PYRIDO(1,2-A)TRIAZINES FROM N-2-PYRIDYL IMIDODIPHENYLTHIOPHOSPHINATES AND CARBON DISULFIDE AS WELL AS PHENYL ISOTHIOCYANATE

1978 ◽  
Vol 9 (1) ◽  
Author(s):  
J. BOEDEKER ◽  
P. KOECKRITZ ◽  
R. KRAFT
Keyword(s):  
Carbon Disulfide ◽  
Phenyl Isothiocyanate ◽  
Reactive Behavior

Reactivity of copper(I) tetrahydroborates toward carbon disulfide and phenyl isothiocyanate. Structures of (PPh3)2Cu(.mu.-S2CSCH2SCS2)Cu(PPh3)2, (PPh3)2Cu(S2COEt), and (PPh3)2Cu(S2CNHPh).CHCl3

1985 ◽  
Vol 24 (6) ◽  
pp. 932-939 ◽  
Author(s):  
Claudio Bianchini ◽  
Carlo A. Ghilardi ◽  
Andrea Meli ◽  
Stefano Midollini ◽  
Annabella Orlandini
Keyword(s):  
Carbon Disulfide ◽  
Phenyl Isothiocyanate

Synthesis and biological activity of new 1,3,4-thiadiazole derivatives

2006 ◽  
Vol 60 (1) ◽  
Author(s):  
A. Aly ◽  
R. El-Sayed
Keyword(s):  
Biological Activity ◽  
Carbon Disulfide ◽  
Acetyl Chloride ◽  
Thioglycolic Acid ◽  
Thiobarbituric Acid ◽  
Aromatic Aldehydes ◽  
Phenyl Isocyanate ◽  
Phenyl Isothiocyanate ◽  
Acid Reaction ◽  
Thiadiazole Derivatives

AbstractThe aminothiadiazole (II) on treatment with aromatic aldehydes yielded Schiff bases, which cyclized to thiazolidinone derivatives by reaction with thioglycolic acid. Reaction of II with phenyl isocyanate and phenyl isothiocyanate afforded the carbamide and carbothiamide derivatives, respectively, which on reaction with malonic acid in acetyl chloride gave barbituric and thiobarbituric acid derivatives. However, reaction of carbon disulfide and methyl iodide with II gave dithiocarbamidate derivative which on treatment with ethylenediamine or o-phenylenediamine gave the condensed N-imidazolylthiadiazolylamine derivatives.

ChemInform Abstract: Reactions of 6-Substituted Benzothiazoline-2-ones Containing Methylene Activated N-Substituents with Carbon Disulfide and Phenyl Isothiocyanate.

ChemInform ◽  
1992 ◽  
Vol 23 (51) ◽  
pp. no-no
Author(s):  
W. DOELLING ◽  
K. KISCHKIES ◽  
D. STROEHL ◽  
F. HEINEMANN ◽  
H. HARTUNG
Keyword(s):  
Carbon Disulfide ◽  
Phenyl Isothiocyanate

Reaktionen von 2-Methyl-1H-benzimidazol mit Schwefelkohlenstoff und Phenylisothiocyanat. Kristall- und Molekülstruktur von 1,1′ -Carbonothioyl-bis(2-methyl-1H-benzimidazol) und 2-Methyl-1-(ethoxycarbonylmethylthio-phenylimino)-1H-benzimidazol / Reactions of 2-Methyl-1 H-benzimidazole with Carbon Disulfide and Phenyl Isothiocyanate. Molecular and Crystal Structures of 1,1′-Carbonothioyl-bis(2-methyl-1 H-benzimidazole) and 2-Methyl-1-(ethoxycarbonylmethylthio-phenylimino)-1 H-benzimidazole

1995 ◽  
Vol 50 (5) ◽  
pp. 837-843 ◽  
Author(s):  
Wolfgang Dölling ◽  
Helmut Hartungb ◽  
Matthias Biedermann
Keyword(s):  
Crystal Structures ◽  
Methyl Iodide ◽  
Carbon Disulfide ◽  
Alkylating Agent ◽  
Sodium Hydride ◽  
Phenyl Isothiocyanate ◽  
Reaction Products ◽  
X Ray ◽  
Molecular And Crystal Structures

Abstract 2-Methyl-1 H-benzimidazole 1 reacts in the presence of two equivalents of sodium hydride in dry DMSO with carbon disulfide to methyl 2-methylbenzimidazole-1-dithiocarboxylate 3 using methyl iodide as alkylating agent, whereas using 1,2-dibromoethane 1,1′-carbonothioyl bis(2-methyl-1 H-benzimidazole) 5 is formed. Compound 1 reacts with phenyl isothiocyanate in the presence of one equivalent of sodium hydride in dry DMF after alkylation to 2-methyl-1-( alkylthio-phenylimino)-1 H-benzimidazoles 6a, 6b. Reaction products 5 and 6b have been identified and structurally characterized by X-ray analysis.

Zum Cycloadditionsverhalten von bis(trifluormethyl)substituierten Nitril-yliden [1]. Positionsselektivität und Regiochemie bei Abfangreaktionen mit Heterokumulenen / Cycloaddition Behaviour of Bis(trifluoromethyl) Substituted Nitrile Ylides [1]. Site Selectivity and Regiochemistry of Trapping Reactions with Heterocumulenes

1982 ◽  
Vol 37 (4) ◽  
pp. 473-485 ◽  
Author(s):  
Klaus Burger ◽  
Herbert Goth ◽  
Ewald Daltrozzo
Keyword(s):  
Carbon Disulfide ◽  
Phenyl Isocyanate ◽  
Phenyl Isothiocyanate ◽  
Cycloaddition Reactions ◽  
Trimethyl Phosphate ◽  
Nitrile Oxides ◽  
Site Selectivity ◽  
Nitrile Imines ◽  
Trapping Reactions

2,2,2-Trimethoxy-3,3-bis(trifluoromethyl)-2,2-dihydro-1,4,2-oxazaphosphol-4-enes on thermolysis undergo a 1,3-dipolar cycloreversion reaction with formation of bis(trifluoromethyl) substituted nitrile ylides and trimethyl phosphate. The nitrile ylides are trapped by N-sulfinyl aniline, phenyl isocyanate, phenyl isothiocyanate, diphenyl ketene, and carbon disulfide. Site selectivity and regiochemistry of the [3 + 2]cycloaddition reactions are described. The results are compared with those obtained from [3 + 2]cycloaddition reactions of nitrile imines, nitrile oxides, alkyl, and aryl substituted nitrile ylides with heterocumulenes.

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