ChemInform Abstract: KINETICS OF OXIDATION OF GLYCINE AND VALINE BY CHLORAMINE-T IN HYDROCHLORIC ACID MEDIUM

1979 ◽  
Vol 10 (20) ◽  
Author(s):  
N. M. M. GOWDA ◽  
D. S. MAHADEVAPPA
Keyword(s):  
Hydrochloric Acid ◽  
Acid Medium ◽  
Kinetics Of Oxidation ◽  
Hydrochloric Acid Medium ◽  
Chloramine T ◽  
Kinetics Of

scholarly journals Kinetics of oxidation of allyl alcohol by chloramine-T in hydrochloric acid medium: effect of high acid concentrations

1975 ◽  
Vol 28 (4) ◽  
pp. 899 ◽  
Author(s):  
DS Mahadevappa ◽  
HMK Naidu
Keyword(s):  
Hydrochloric Acid ◽  
Allyl Alcohol ◽  
Alcohol Concentration ◽  
Medium Effect ◽  
Kinetics Of Oxidation ◽  
First Order ◽  
Hydrochloric Acid Medium ◽  
Entropy Of Activation ◽  
Chloramine T ◽  
Kinetics Of

The kinetics of oxidation of allyl alcohol by chloramine-T in presence of hydrochloric acid(0.15-0.29M) has been studied. At 0�C the rate is first order with respect to chloramine-T, second order in [H+] and independent of the alcohol concentration. The energy of activation and entropy of activation of the reaction have been found to be 55.6 kJ mol -1 and -153 J K-1 respectively. A mechanism is proposed.

Kinetics of oxidation of hypophosphite ion by Au(III) in hydrochloric acid medium

Polyhedron ◽  
1983 ◽  
Vol 2 (10) ◽  
pp. 983-986 ◽  
Author(s):  
Kalyan Kali Sengupta ◽  
Biswanath Basu ◽  
Shipra Sengupta ◽  
Sanghamitra Nandi
Keyword(s):  
Hydrochloric Acid ◽  
Acid Medium ◽  
Kinetics Of Oxidation ◽  
Hydrochloric Acid Medium ◽  
Kinetics Of

A reinvestigation of the reaction between Prop-2-en-1-ol and chloramine-T in hydrochloric acid medium

1983 ◽  
Vol 36 (1) ◽  
pp. 203 ◽  
Author(s):  
KP Herlihy
Keyword(s):  
Hydrochloric Acid ◽  
Acid Medium ◽  
Unsaturated Alcohol ◽  
Molecular Chlorine ◽  
First Order ◽  
Hydrochloric Acid Medium ◽  
Chloramine T

Contrary to a previous report the reaction of prop-2-en-1-ol with chloramine-T in 1 M HCl gives 2,3-dichloropropan-1-ol not prop-2-en-1-al. For HCl concentrations of 0.075 M and higher the reaction is of first order each with respect to the concentration of chloramine-T, H+ and Cl- ions, but independent of the alcohol. As chloroamines in these conditions are known to give chlorine, it is proposed that the reaction involves the addition to the unsaturated alcohol of molecular chlorine which is produced by a prior, rate-determining reaction between H+ and Cl- ions with chloramine-T.

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