ChemInform Abstract: ANODIC DECARBOXYLATION OF TETRATHIAFULVALENE MONOCARBOXYLIC ACID AND ITS CONJUGATE BASE. AN EXAMPLE OF AN AUTOCATALYTIC ECE MECHANISM

1980 ◽  
Vol 11 (41) ◽  
Author(s):  
K. A. IDRISS ◽  
J. Q. CHAMBERS ◽  
D. C. GREEN
Keyword(s):  
Monocarboxylic Acid ◽  
Ece Mechanism ◽  
Conjugate Base

Electroanalytical chemistry of vanadium complexes. Comparison of the voltammetric features of amavadine with those of the vanadium complexes with iminodiacetic acid and methyliminodiacetic acid

1989 ◽  
Vol 54 (1) ◽  
pp. 53-63 ◽  
Author(s):  
Roland Meier ◽  
Harald Frank ◽  
Reinhard Kirmse ◽  
Reiner Salzer ◽  
Joachim Stach ◽  
...  
Keyword(s):  
Iminodiacetic Acid ◽  
Vanadium Complexes ◽  
Reduction Mechanism ◽  
Reversible Process ◽  
Electroanalytical Chemistry ◽  
Probable Explanation ◽  
Chemical Sense ◽  
Ece Mechanism ◽  
Methyliminodiacetic Acid

The voltammetric behaviour of amavadine (AV) was found to be considerably different from that of the complexes of VO2+ with methyliminodiacetic acid (MIDA) and iminodiacetic acid (IDA). To get an insight in the rather complicated reduction mechanism of the latter complexes the reductions of V(III) (MIDA) and V(III) (IDA) have been studied for comparison. The species V(III) (MIDA)2 and V(III) (IDA)2 are reduced to the appropriate V(II) complexes in a chemically reversible process. VO(MIDA)2 and VO(IDA)2 are reduced to the same complexes via an ECE mechanism. The investigation of the electroreduction of AV shows that this process is not reversible in the chemical sense. As a probable explanation, the conclusion was drawn that AV and the usual V(IV)O-iminocarboxylato complexes differ in their structures.

Uptake of phenoxyacetic acid derivatives into Caco-2 cells by the monocarboxylic acid transporters

2009 ◽  
Vol 189 (2) ◽  
pp. 102-109 ◽  
Author(s):  
Osamu Kimura ◽  
Kensuke Tsukagoshi ◽  
Tetsuya Endo
Keyword(s):  
Monocarboxylic Acid ◽  
Phenoxyacetic Acid

HPLC enantiomer separation of a chiral 1,4-dihydropyridine monocarboxylic acid

2004 ◽  
Vol 35 (2) ◽  
pp. 259-266 ◽  
Author(s):  
Michael Lämmerhofer ◽  
Olle Gyllenhaal ◽  
Wolfgang Lindner
Keyword(s):  
Enantiomer Separation ◽  
Monocarboxylic Acid
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