ChemInform Abstract: PHOTOELECTRON SPECTRA OF GROUP V COMPOUNDS. VIII. STIBORANES ME3SBX2 (X = ME, , CL, BR, I) AND ANTIMONY PENTACHLORIDE - COMPARED WITH GROUP VB ANALOGS PENTAMETHYLTANTALUM, TANTALUM PENTACHLORIDE, AND NIOBIUM PENTACHLORIDE

1982 ◽  
Vol 13 (16) ◽  
Author(s):  
S. ELBEL ◽  
H. TOM DIECK
Keyword(s):  
Photoelectron Spectra ◽  
Antimony Pentachloride ◽  
Group V ◽  
Niobium Pentachloride

Photoelektronenspektren von Verbindungen der V. Hauptgruppe, VI Methyl- und Trifluormethyl-Cyanphosphine, MenP(CN)3-n und (CF3)nP(CN)3-n (n = 0, 1, 2, 3). / Photoelectron Spectra of Group V Compounds, VI Methyl- and Trifluoromethyl-Cyanophosphines, MenP(CN)3-n and (CF3)nΡ(CN)3-n (n = 0, 1, 2, 3)

1976 ◽  
Vol 31 (11) ◽  
pp. 1472-1479 ◽  
Author(s):  
Susanne Elbel ◽  
Heindirk Tom Dieck ◽  
Reinhard Demuth
Keyword(s):  
Electronic Structures ◽  
Photoelectron Spectra ◽  
Group V ◽  
Inductive Effects ◽  
Cyano Compounds

The He I photoelectron spectra of the series RnP(CN)3-n (R = Me, CF3; n = 0, 1, 2, 3) and of Me2ECN (E = N, P, As) are interpreted. The PE assignments are based on the comparison with the PE data of analogous halogeno and hydrogen derivatives as well as related cyano compounds and on simple MO considerations (composite molecule-approach). Hyperconjugative and inductive effects of the substituents CN, Me, F, Cl, and especially CF3 are assessed. The various effects of changing substituents or central atoms within the series are used to confirm the interpretation. The differing electronic structures of halogeno and cyano (pseudohalogeno) compounds are discussed on the basis of their PE spectra

Photoelectron spectra of group V compounds. The elements: Sb4

1984 ◽  
Vol 109 (3) ◽  
pp. 312-316 ◽  
Author(s):  
S. Elbel ◽  
J. Kudnig ◽  
M. Grodzicki ◽  
H.J. Lempka
Keyword(s):  
Photoelectron Spectra ◽  
Group V

Photoelectron spectra and valence shell orbital structures of groups V and VI hydrides

1972 ◽  
Vol 326 (1565) ◽  
pp. 181-197 ◽  
Keyword(s):  
Vibrational Structure ◽  
Molecular Orbitals ◽  
Ionization Potentials ◽  
Photoelectron Spectra ◽  
Valence Shell ◽  
Group V ◽  
Bond Angles ◽  
Vertical Ionization Potentials

Photoelectron spectra are reported for the hydrides of group v and vi elements. Vibrational structure has been observed in bands associated with all but the inner-most valence orbitals. It has been used to obtain changes in bond angles or bond distances which result from the ionization of successive molecular orbitals. Ionization from the inner (la 1 ) orbitals of the hydrides has been observed using He II 304 Å+ radiation. From these data vertical ionization potentials have been derived for all the valence orbitals of the hydrides XH, XH 2 , XH 3 and XH 4 for which the corresponding united atoms are Ne, A, Kr and Xe. Graphs of these values are used to show the effects of inner shells on the valence orbitals.

Calculation of photoelectron spectra of the trihalides of group v elements

1984 ◽  
Vol 33 (2) ◽  
pp. 93-105 ◽  
Author(s):  
Min Xin ◽  
Lue-Yung Chow Chiu ◽  
Du Li ◽  
Yuh-Kang Pan
Keyword(s):  
Photoelectron Spectra ◽  
Group V

Photoelectron spectra of group V compounds, As4 and As2

1981 ◽  
Vol 53 ◽  
pp. L101-L102 ◽  
Author(s):  
Susanne Ebel ◽  
Heindirk Tom Dieck ◽  
Horst Walther ◽  
J. Krizek
Keyword(s):  
Photoelectron Spectra ◽  
Group V
Sign in / Sign up

Export Citation Format

Share Document