ChemInform Abstract: PREPARATION, SEPARATION, AND CHARACTERIZATION OF TWO NEW SERIES OF MIXED-LIGAND EIGHT-COORDINATE TUNGSTEN(IV) COMPLEXES CONTAINING THE PAIRS OF BIDENTATE LIGANDS 2-MERCAPTOPYRIMIDINE-5-TERT-BUTYL-2-MERCAPTOPYRIMIDINE AND 5-METHYLPICOL

1985 ◽  
Vol 16 (42) ◽  
Author(s):  
C. J. DONAHUE ◽  
E. C. KOSINSKI ◽  
V. A. MARTIN
Keyword(s):  
Mixed Ligand ◽  
Bidentate Ligands ◽  
Tert Butyl

Spectral and Thermal Studies on Some New Anionic Mixed Alkyldithiocarbonato-Oxinato Transition Metal Complexes

1989 ◽  
Vol 44 (3) ◽  
pp. 323-326 ◽  
Author(s):  
Aref A. M. Aly ◽  
Asma I. El-Said
Keyword(s):  
Transition Metal ◽  
Transition Metal Complexes ◽  
Thermal Studies ◽  
Mixed Ligand ◽  
Magnetic Data ◽  
Bidentate Ligands ◽  
Conductivity Data ◽  
Anionic Ligands ◽  
Ionic Nature

The preparation and characterization of some anionic mixed ligand com plexes of Co(II), Ni(II) and Cu(II) containing the two anionic ligands alkyldithiocarbonate and oxinate are reported. The ionic nature of the complexes was inferred from the conductivity data. Alkyldithiocarbonates act in these complexes as bidentate ligands. Based on the spectroscopic and magnetic data the complexes appear to possess pseudo-octahedral metal coordination.

Ligand isomerism in Pt(II) complexes – structural aspects

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Milan Melník ◽  
Peter Mikuš
Keyword(s):  
Mixed Ligand ◽  
Bidentate Ligands ◽  
Trans Isomers ◽  
Mean Values ◽  
Bite Angle ◽  
Coordination Spheres ◽  
Structural Aspects

Abstract This review has focused on ligand isomers in Pt(II) complexes. There are a variety of inner coordination spheres about the platinum(II) atom (PtN4, PtN2Cl2, PtP2Cl2, PtPNC2, PtPNCl2, PtP2CBr, PtP2CS), build up by mono- and bidentate ligands. The bidentate ligands create a variety of metallocyclic rings. The L–Pt–L bite angle (mean values) open in the sequence: 73.1° (PNP) < 78.7° (NC2C) < 80.4° (NC2N) < 86.4° (PC2P) < 86.7° (PNNP) < 93.0° (CC3S). There are three types of isomers: ligand, mixed – (ligand + distortion), and mixed – (ligand + cis-trans), isomers, which are rarity.

Redox Chemistry of (1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7- triazacyclononane)ruthenium(III), [RuIIIL]:  Synthesis and Characterization of [RuII2(L−L)](BPh4)4·10CH3CN and [LRuRuRuL](PF6)2·H2O

1999 ◽  
Vol 38 (22) ◽  
pp. 5131-5138 ◽  
Author(s):  
Belén Albela ◽  
Eberhard Bothe ◽  
Oliver Brosch ◽  
Katsura Mochizuki ◽  
Thomas Weyhermüller ◽  
...  
Keyword(s):  
Redox Chemistry ◽  
Synthesis And Characterization ◽  
Tert Butyl

Synthesis and structural characterization of a novel Re[P][NN][S][SO] mixed ligand rhenium(III) complex

2003 ◽  
Vol 346 ◽  
pp. 270-274 ◽  
Author(s):  
D. Papagiannopoulou ◽  
I.C. Pirmettis ◽  
M. Pelecanou ◽  
Ch. Tsoukalas ◽  
C.P. Raptopoulou ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Mixed Ligand

scholarly journals Electrochemical Characterization of Biochemically Active Cu(II) Mixed Ligand Complex with Histidine and Cysteine

2016 ◽  
Vol 29 (2) ◽  
pp. 392-397 ◽  
Author(s):  
Marina Mlakar ◽  
Sonja Pavković ◽  
Lidija-Marija Tumir ◽  
Petra Vukosav ◽  
Blaženka Gašparović
Keyword(s):  
Mixed Ligand Complex ◽  
Mixed Ligand ◽  
Electrochemical Characterization ◽  
Ligand Complex
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