ChemInform Abstract: Temperature Dependence of the Transition-State Structure for the Disproportionation of Hydrogen Atom with Ethyl Radical.

1986 ◽  
Vol 17 (3) ◽  
Author(s):  
C. JUN. DOUBLEDAY ◽  
J. MCIVER ◽  
M. PAGE ◽  
T. ZIELINSKI
Keyword(s):  
Hydrogen Atom ◽  
Transition State ◽  
Temperature Dependence ◽  
State Structure ◽  
Transition State Structure ◽  
Ethyl Radical

ρ as a quantitative measure of transition state structure

1979 ◽  
Vol 57 (3) ◽  
pp. 255-257 ◽  
Author(s):  
Bo-Long Poh
Keyword(s):  
Free Radicals ◽  
Hydrogen Atom ◽  
Transition State ◽  
Nucleophilic Substitution ◽  
Electrophilic Substitution ◽  
Quantitative Measure ◽  
Hydrogen Atom Abstraction ◽  
State Structure ◽  
Transition State Structure ◽  
Substitution Reactions

The values of the Brønsted exponent for several examples of nucleophilic substitution reactions, aromatic electrophilic substitution reactions, and hydrogen atom abstraction from toluene by free radicals have been calculated from the ρ values of the corresponding reactions. The magnitude of the Brønsted exponent is shown to indicate the degree of charge developed in the transition state structure.

Rearrangement of chorismate to prephenate. Use of chorismate mutase inhibitors to define the transition state structure

Biochemistry ◽  
1977 ◽  
Vol 16 (22) ◽  
pp. 4848-4852 ◽  
Author(s):  
P. R. Andrews ◽  
E. N. Cain ◽  
E. Rizzardo ◽  
G. D. Smith
Keyword(s):  
Transition State ◽  
Chorismate Mutase ◽  
State Structure ◽  
Transition State Structure

Conservation of Transition State Structure in Fast Folding Peripheral Subunit-Binding Domains

2008 ◽  
Vol 383 (1) ◽  
pp. 224-237 ◽  
Author(s):  
Timothy D. Sharpe ◽  
Neil Ferguson ◽  
Christopher M. Johnson ◽  
Alan R. Fersht
Keyword(s):  
Transition State ◽  
State Structure ◽  
Transition State Structure ◽  
Binding Domains
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