ChemInform Abstract: Enantioselective Synthesis of sec-Allyl Alcohols by Catalytic Asymmetric Addition of Divinylzinc to Aldehydes.

ChemInform ◽  
1989 ◽  
Vol 20 (18) ◽  
Author(s):  
W. OPPOLZER ◽  
R. N. RADINOV
Keyword(s):  
Enantioselective Synthesis ◽  
Asymmetric Addition ◽  
Catalytic Asymmetric ◽  
Allyl Alcohols

Enantioselective synthesis of α,α-disubstituted α-amino acids via direct catalytic asymmetric addition of acetonitrile to α-iminoesters

2016 ◽  
Vol 14 (41) ◽  
pp. 9725-9730 ◽  
Author(s):  
Shaoquan Lin ◽  
Naoya Kumagai ◽  
Masakatsu Shibasaki
Keyword(s):  
Amino Acids ◽  
Enantioselective Synthesis ◽  
Asymmetric Addition ◽  
Carbene Complexes ◽  
Enantioselective Addition ◽  
Catalytic Asymmetric

Chiral N-heterocyclic carbene complexes of [Ir(cod)(OMe)]2 in combination with Barton's base enabled direct enantioselective addition of acetonitrile to α-iminoesters.

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