An efficient rhodium(III)-catalyzed direct C-H oxidative annulation of isoquinolones with allyl alcohols as C1 synthons has been successfully developed. This protocol enables the straightforward synthesis of structurally diverse isoindolo[2,1-b]isoquinolin-5(7H)-ones with...
Ir(III)-catalyzed C−H alkylation of BINOL units has been well examined by allyl alcohols as coupling partners. Under the advantage of pyridine guiding group, the efficient protocol allows the rapid synthesis...
An efficient oxytrifluoromethylation of allyl alcohols has been developed using Togni’s reagent II as a trifluoromethylation reagent and cuprous chloride as a catalyst. This reaction proceeded through a one-pot process of trifluoromethylation followed by nucleophilic attack of the vicinal hydroxyl group. This strategy features good diastereoselectivity and broad substrate scope, which provides a facile access to various α-CF3-substituted epoxides.
Bulky Cyclometalated Ruthenium Nitrates for Challenging Z‐Selective Metathesis: Efficient One‐Step Access to α‐Oxygenated Z‐Olefins from Acrylates and Allyl Alcohols
