Enantioselective Synthesis of Protected Amines by the Catalytic Asymmetric Addition of Hydrazoic Acid to Ketenes.

ChemInform ◽  
2007 ◽  
Vol 38 (39) ◽  
Author(s):  
Xing Dai ◽  
Takashi Nakai ◽  
Jan A. C. Romero ◽  
Gregory C. Fu
Keyword(s):  
Enantioselective Synthesis ◽  
Hydrazoic Acid ◽  
Asymmetric Addition ◽  
Catalytic Asymmetric

Enantioselective Synthesis of Protected Amines by the Catalytic Asymmetric Addition of Hydrazoic Acid to Ketenes

2007 ◽  
Vol 119 (23) ◽  
pp. 4445-4447 ◽  
Author(s):  
Xing Dai ◽  
Takashi Nakai ◽  
Jan A. C. Romero ◽  
Gregory C. Fu
Keyword(s):  
Enantioselective Synthesis ◽  
Hydrazoic Acid ◽  
Asymmetric Addition ◽  
Catalytic Asymmetric

Enantioselective synthesis of α,α-disubstituted α-amino acids via direct catalytic asymmetric addition of acetonitrile to α-iminoesters

2016 ◽  
Vol 14 (41) ◽  
pp. 9725-9730 ◽  
Author(s):  
Shaoquan Lin ◽  
Naoya Kumagai ◽  
Masakatsu Shibasaki
Keyword(s):  
Amino Acids ◽  
Enantioselective Synthesis ◽  
Asymmetric Addition ◽  
Carbene Complexes ◽  
Enantioselective Addition ◽  
Catalytic Asymmetric

Chiral N-heterocyclic carbene complexes of [Ir(cod)(OMe)]2 in combination with Barton's base enabled direct enantioselective addition of acetonitrile to α-iminoesters.

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