ChemInform Abstract: Synthesis and Dynamic NMR Studies of Pentafluorobenzenethiolate Complexes of Molybdenum and Tungsten. The Crystal and Molecular Structures of (W(SC6F5)3(CO)(η5-C5H5))·0.5 CH2Cl2 and (N(PPh3)2)(Mo(SC6F5)4(η5-C5H5)).

ChemInform ◽  
1990 ◽  
Vol 21 (15) ◽  
Author(s):  
W. A. W. A. BAKAR ◽  
J. L. DAVIDSON ◽  
W. E. LINDSELL ◽  
K. J. MCCULLOUGH
Keyword(s):  
Molecular Structures ◽  
Dynamic Nmr ◽  
Nmr Studies ◽  
Crystal And Molecular Structures ◽  
And Tungsten

ChemInform Abstract: Cadmium Polysulfide Complexes, (Cd(Sx)(Sy))2-: Syntheses, Crystal and Molecular Structures, and 113Cd NMR Studies.

ChemInform ◽  
1989 ◽  
Vol 20 (34) ◽  
Author(s):  
R. M. H. BANDA ◽  
I. G. DANCE ◽  
T. D. BAILEY ◽  
D. C. CRAIG ◽  
M. L. SCUDDER
Keyword(s):  
Molecular Structures ◽  
Nmr Studies ◽  
Crystal And Molecular Structures

Seven-coordinate hydride complexes of molybdenum and tungsten. Crystal and molecular structures of WH(Cl)(CO)2(PMe3)3

1993 ◽  
Vol 12 (10) ◽  
pp. 4228-4233 ◽  
Author(s):  
Leopoldo Contreras ◽  
Angeles Monge ◽  
Antonio Pizzano ◽  
Caridad Ruiz ◽  
Luis Sanchez ◽  
...  
Keyword(s):  
Molecular Structures ◽  
Hydride Complexes ◽  
Crystal And Molecular Structures ◽  
Tungsten Crystal ◽  
And Tungsten

Distannylchalkogenide: 119Sn-NMR-Untersuchungen und die Kristall- und Molekülstrukturen von Bis(tri-tert-butylstannyl)oxid und Bis(tribenzylstannyl)sulfid / Distannylchalcogenides: 119Sn NMR Studies and the Crystal and Molecular Structures of Bis(tri-tert-butylstannyl)oxide and Bis(tribenzylstannyl)sulfide

1987 ◽  
Vol 42 (4) ◽  
pp. 387-394 ◽  
Author(s):  
Susanna Kerschl ◽  
Bernd Wrackmeyer ◽  
Detlef Männig ◽  
Heinrich Nöth ◽  
Rudolf Staudigl
Keyword(s):  
Bond Angle ◽  
Linear Structure ◽  
Molecular Structures ◽  
Coupling Constants ◽  
X Ray Diffraction ◽  
Nmr Studies ◽  
X Ray ◽  
Crystal And Molecular Structures ◽  
119Sn Nmr ◽  
Geminal Coupling

Bis(triorganylstannyl)chalcogenides (O, S, Se) have been studied by 119Sn NMR in solution. In most cases the magnitude of the geminal coupling constants 2J(SnSn) are indicative of a bent arrangement SnXSn (X = O, S, Se). The exception is bis(tri-tert-butylstannyl)oxide for which the linear structure S n - O - S n as determined by X-ray diffraction in the solid state is preserved in solution. The trend of the coupling constants 2J(SnSn) depending on X and on the bond angle SnXSn suggests that 2J(SnOSn) > 0 and 2J(SnSSn), 2J(SnSeSn) <0. The X-ray diffraction study of bis(tribenzylstannyl)sulfide shows a bent arrangement (∢SnSSn 105.52(14)°) in contrast to the corresponding oxide.

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