Study of Triple System Calcium Iodide-HMTA-Water

Research relevance: synthesis, physicochemical studies of complexes bioactivity with salts of biometals and organic ligands are of great interest for bio-coordination chemistry. Materials and research methods: isothermal method was used to study heterogeneous equilibria at 25 °C. The concentration limits of compounds existence and the types of their solubility have been established. Research objectives: to investigate compounds of hexamethylenetetramine with salts of biometals with organic ligands in order to reduce toxicity, increase the bioactivity and bioavailability of coordination compounds. Research results: concentration limits of compounds existence and types of their solubility have been established. Conclusions: in obtained complexes, HMTA ligand contains four equivalent electron donor nitrogen atoms.

A fluorinated 2D magnetic coordination polymer

Herein we show the versatility of coordination chemistry to design and expand a family of 2D materials by incorporating F groups at the surface of the layers. Through the use...

Synthesis, structure, and coordination chemistry of a neutral pyrrolyl functionalized amidinate ligand

A new o-phenylene-bridged ligand incorporating neutral pyrrolyl and amidino moieties with the formula 2-(2,5-Me2C4H2N)C6H4NHC(Ph)=NDipp (HL, Dipp = 2,6-iPr2C6H3) was prepared via the reaction of 2-(2,5-dimethylpyrrolyl)aniline with 2,6-iPr2C6H3N=C(Cl)C6H5. Metalation of the...

Palladium(II) Complexes of Bis(diphosphene) with the Different Coordination Behavior

Organophosphorus compounds possessing the P−P double-bond character are intriguing materials in coordination chemistry because it is possible to form a variety of coordination modes from the π-bond in addition to...

Terminal and Internal Alkyne Complexes and Azide-Alkyne Cycloaddition Chemistry of Copper(I) Supported by a Fluorinated Bis(pyrazolyl)borate

Copper plays an important role in alkyne coordination chemistry and transformations. This report describes the isolation and full characterization of a thermally stable, copper(I) acetylene complex using a highly fluorinated bis(pyrazolyl)borate ligand support. Details of the related copper(I) complex of HCºCSiMe3 are also reported. They are three-coordinate copper complexes featuring η2-bound alkynes. Raman data show significant red-shifts in CºC stretch of [H2B(3,5-(CF3)2Pz)2]Cu(HCºCH) and [H2B(3,5-(CF3)2Pz)2]Cu(HCºCSiMe3) relative to those of the corresponding alkynes. Computational analysis using DFT indicates that the Cu(I) alkyne interaction in these molecules is primarily of the electrostatic character. The π-backbonding is the larger component of the orbital contribution to the interaction. The dinuclear complexes such as Cu2(μ-[3,5-(CF3)2Pz])2(HCºCH)2 display similar Cu-alkyne bonding features. The mononuclear [H2B(3,5-(CF3)2Pz)2]Cu(NCMe) complex catalyzes [3+2] cycloadditions between tolyl azide and a variety of alkynes including acetylene. It is comparatively less effective than the related trinuclear copper catalyst {μ-[3,5-(CF3)2Pz]Cu}3 involving bridging pyrazolates.