ChemInform Abstract: Self-Diffusion and 13C Relaxation of Self-Associated 1,10- Phenanthroline.

ChemInform ◽  
2010 ◽  
Vol 22 (25) ◽  
pp. no-no
Author(s):  
M. GERINGER ◽  
H. GRUBER ◽  
H. STERK
1983 ◽  
Vol 80 ◽  
pp. 315-323 ◽  
Author(s):  
Marc Lindheimer ◽  
Jean-Claude Montet ◽  
Roselyne Bontemps ◽  
Jacques Rouviere ◽  
Bernard Brun

1976 ◽  
Vol 37 (C7) ◽  
pp. C7-538-C7-539
Author(s):  
M. GRUPP ◽  
H. ACKERMANN ◽  
D. DUBBERS ◽  
H. GRUPP ◽  
P. HEITJANS ◽  
...  
Keyword(s):  

1986 ◽  
Vol 47 (C2) ◽  
pp. C2-337-C2-340 ◽  
Author(s):  
G. KOZLOWSKI ◽  
A. CISZEWSKI ◽  
W. SWIECH
Keyword(s):  

1986 ◽  
Vol 47 (C2) ◽  
pp. C2-331-C2-336 ◽  
Author(s):  
G. L. KELLOGG
Keyword(s):  

Author(s):  
Nicola Molinari ◽  
Jonathan P. Mailoa ◽  
Boris Kozinsky

We show that strong cation-anion interactions in a wide range of lithium-salt/ionic liquid mixtures result in a negative lithium transference number, using molecular dynamics simulations and rigorous concentrated solution theory. This behavior fundamentally deviates from the one obtained using self-diffusion coefficient analysis and agrees well with experimental electrophoretic NMR measurements, which accounts for ion correlations. We extend these findings to several ionic liquid compositions. We investigate the degree of spatial ionic coordination employing single-linkage cluster analysis, unveiling asymmetrical anion-cation clusters. Additionally, we formulate a way to compute the effective lithium charge that corresponds to and agrees well with electrophoretic measurements and show that lithium effectively carries a negative charge in a remarkably wide range of chemistries and concentrations. The generality of our observation has significant implications for the energy storage community, emphasizing the need to reconsider the potential of these systems as next generation battery electrolytes.<br>


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