ChemInform Abstract: Solvolysis of Benzylic Alcohols. Mechanism and Stereochemistry of the Acid Methanolysis of Diastereoisomeric trans-1,2,3,4,4a,10a- Hexahydrophenanthren-9-ol and 4-tert.-Butyl-1-phenylcyclohexanol.

ChemInform ◽  
2010 ◽  
Vol 22 (36) ◽  
pp. no-no
Author(s):  
M. CHINI ◽  
P. CROTTI
Keyword(s):  
Benzylic Alcohols ◽  
Tert Butyl ◽  
Acid Methanolysis

Catalytic condensation process for the preparation of organic peroxides from tert-butyl hydroperoxide and benzylic alcohols

2006 ◽  
Vol 315 ◽  
pp. 150-152 ◽  
Author(s):  
Aliakbar Tarlani ◽  
Abdelkhalek Riahi ◽  
Mansour Abedini ◽  
Mostafa Mohammadpour Amini ◽  
Jacques Muzart
Keyword(s):  
Condensation Process ◽  
Organic Peroxides ◽  
Butyl Hydroperoxide ◽  
Benzylic Alcohols ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Catalytic Condensation

Oxidation of primary and secondary benzylic alcohols with hydrogen peroxide and tert-butyl hydroperoxide catalyzed by a “helmet” phthalocyaninato iron complex in the absence of added organic solvent

2014 ◽  
Vol 43 (48) ◽  
pp. 17899-17903 ◽  
Author(s):  
Brian M. Peterson ◽  
Morgan E. Herried ◽  
Rachel L. Neve ◽  
Robert W. McGaff
Keyword(s):  
Hydrogen Peroxide ◽  
Organic Solvent ◽  
Alcohol Oxidation ◽  
Iron Complex ◽  
Butyl Hydroperoxide ◽  
Benzylic Alcohols ◽  
Effective Catalyst ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Benzylic Alcohol

A “helmet” metallophthalocyanine of iron(iii) is a very effective catalyst for benzylic alcohol oxidation in the absence of added organic solvent.

scholarly journals Oxidations of Alkylbenzenes with Dimethyldioxirane

1991 ◽  
Vol 46 (9) ◽  
pp. 1223-1226 ◽  
Author(s):  
Dietmar Kuck ◽  
Andreas Schuster
Keyword(s):  
Steric Hindrance ◽  
Reaction Centre ◽  
Benzylic Alcohols ◽  
Tert Butyl

The oxidation of various alkylbenzenes (1-17) with excess dimethyldioxirane (DMDO) in homogeneous acetone solutions has been studied. In general, the benzylic methylene and methine C–H bonds were oxidized to give the corresponding phenones and tertiary benzylic alcohols, respectively, in relatively low yields. Whereas a tert-butyl substituent at the reaction centre leads to very low conversion due to steric hindrance, the presence of additional phenyl groups appears to favour the oxidation in most, but not all cases. Di- and triphenylmethane (4 and 14) were found to be considerably less reactive than cis-decalin. By contrast, the intramolecular competetive oxidation of isobutylbenzene (19) and 1-methyl-4-phenylcyclohexanes (20) reveals that the benzylic C–H bonds are slightly more reactive than the tertiary ones at remote positions.

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