ChemInform Abstract: Synthesis, X-Ray Crystal Structure, and Multistage Redox Properties of a Severely-Distorted Tetrathiafulvalene Donor.

ChemInform ◽  
2010 ◽  
Vol 23 (26) ◽  
pp. no-no
Author(s):  
M. R. BRYCE ◽  
M. A. COFFIN ◽  
M. B. HURSTHOUSE ◽  
A. I. KARAULOV ◽  
K. MUELLEN ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Redox Properties ◽  
X Ray

Crystal Structure, Spectroscopic and Redox Properties of Copper(II) Bis{2-[(2,6-dimethylphenyl)iminomethyl-3-methoxyphenolate]}

2007 ◽  
Vol 62 (9) ◽  
pp. 1133-1138 ◽  
Author(s):  
Veli T. Kasumov ◽  
Ibrahim Uçar ◽  
Ahmet Bulut ◽  
Fevzi Kösal
Keyword(s):  
Crystal Structure ◽  
Title Complex ◽  
Redox Properties ◽  
Orthorhombic Space Group ◽  
Long Distance ◽  
X Ray ◽  
X Ray Crystallography ◽  
Square Planar ◽  
Planar Molecules ◽  
Exchange Interaction Parameter

The coordination chemistry of N-(2,6-di-methylphenyl)-2-hydroxy-3-methoxybenzaldimine (1) with Cu(II) has been investigated by X-ray crystallography, electronic and EPR spectroscopies, as well as by electro- and magnetochemistry. The title complex 2 crystallizes in the orthorhombic space group P212121 (a = 8.1538, b = 17.7466, c =19.8507 Å). The mononuclear square-planar molecules 2 featuring trans-N2O2 coordination are connected via weak intermolecular C-H· · ·π interactions into infinite chains parallel to the a axis. Although the intermolecular Cu· · ·Cu separations within individual chains and between chains are very long (8.154 and 9.726 Å ), the exchange interaction parameter G = 2.03 < 4, estimated from solid state EPR spectra, suggests the existence of long-distance superexchange pathways between adjacent Cu(II) centers. The electronic and electrochemical features of the compound are also discussed.

Synthesis, x-ray crystal structure and multistage redox properties of a severely-distorted tetrathiafulvalene donor

1991 ◽  
Vol 32 (42) ◽  
pp. 6029-6032 ◽  
Author(s):  
Martin R. Bryce ◽  
Malcolm A. Coffin ◽  
Michael B. Hursthouse ◽  
A.I. Karaulov ◽  
Klaus Müllen ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Redox Properties ◽  
X Ray

Crystal structure of gluconate bound iron(iii) complex: synthesis, characterization and redox properties of the complex in aqueous solution

2018 ◽  
Vol 42 (18) ◽  
pp. 15088-15096
Author(s):  
Christopher D. Stewart ◽  
Hadi Arman ◽  
Brenda Benavides ◽  
Ghezai T. Musie
Keyword(s):  
Crystal Structure ◽  
Aqueous Solution ◽  
Single Crystal ◽  
Redox Properties ◽  
Water Soluble ◽  
X Ray

The synthesis, characterization and redox properties of the first single crystal X-ray characterized, water soluble bis-gluconato-tetra-iron(iii) containing complex has been reported.

Synthesis, X-ray crystal structure, and redox properties of Cp*Ru(NO)(mnt)

1994 ◽  
Vol 483 (1-2) ◽  
pp. 7-15 ◽  
Author(s):  
Kaiyuan Yang ◽  
Simon G. Bott ◽  
Michael G. Richmond
Keyword(s):  
Crystal Structure ◽  
Redox Properties ◽  
X Ray
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