ChemInform Abstract: Highly Stereoselective Synthesis of α,β-Unsaturated Ketones by CeCl3 Mediated Addition of Grignard Reagents to β-Enamino Ketones.

ChemInform ◽  
2010 ◽  
Vol 25 (31) ◽  
pp. no-no
Author(s):  
G. BARTOLI ◽  
C. CIMARELLI ◽  
E. MARCANTONI ◽  
G. PALMIERI ◽  
M. PETRINI
Keyword(s):  
Stereoselective Synthesis ◽  
Grignard Reagents ◽  
Unsaturated Ketones ◽  
Enamino Ketones

Diastereoselective Synthesis of Morpholine Derivatives from Grignard Reagents and N-Sulfinyl Imines

Synlett ◽  
2021 ◽  
Author(s):  
Eric P. A. Talbot ◽  
Joseph M. Bateman ◽  
Diana Chan ◽  
Mustafa Moroglu ◽  
Benjamin Rahemtulla
Keyword(s):  
Grignard Reagent ◽  
Stereoselective Synthesis ◽  
Grignard Reagents ◽  
Diastereoselective Synthesis ◽  
Step Process ◽  
Diastereoselective Addition ◽  
Morpholine Derivatives

The stereoselective synthesis of C3-substituted morpholine derivatives has been achieved through a two-step process involving diastereoselective addition of a Grignard reagent to a sulfinyl imine, followed by cyclization.

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