ChemInform Abstract: Phase-Transfer-Catalyzed Additions. Part 11. Convenient Synthesis of 2, 3,5-Triaryl-5-oxopentanoic Acids and of Their tert-Butyl Esters.

ChemInform ◽  
2010 ◽  
Vol 25 (34) ◽  
pp. no-no
Author(s):  
V. DRYANSKA ◽  
A. POPOVICH
Keyword(s):  
Phase Transfer ◽  
Tert Butyl ◽  
Butyl Esters ◽  
Convenient Synthesis

Phase-transfer Catalysed Reactions of Mono- and disubstituted N-(benzylidene)-benzylamines with cinnamic acid derivatives

2000 ◽  
Vol 2000 (3) ◽  
pp. 103-105 ◽  
Author(s):  
Iva Pashkuleva ◽  
Veneta Dryanska ◽  
Silvia Angelova ◽  
Svetlana Simova
Keyword(s):  
Cinnamic Acid ◽  
Phase Transfer ◽  
Cinnamic Acid Derivatives ◽  
Tert Butyl ◽  
Butyl Esters

Tert-butyl esters 3 and 3-cyanopyrrolidines 6 are prepared by phase-transfer-catalysed reactions of symmetrical 4,4′-disubstituted N-(benzylidene)benzylamines with tert-butyl cinnamate and α-phenylcinnamonitrile, respectively; similar reactions of mono-substitited N-(benzylidene)benzylamines afforded mixtures of compounds 3, respectively 6, and their regioisomers 3(A) and 6(A).

A Simple and Convenient Synthesis of ω-tert-Butyl Esters of Fmoc-Aspartic and Fmoc-Glutamic Acids

Synthesis ◽  
1990 ◽  
Vol 1990 (07) ◽  
pp. 571-572 ◽  
Author(s):  
Gilles Lajoie ◽  
Anna Crivici ◽  
J. Gordon Adamson
Keyword(s):  
Tert Butyl ◽  
Butyl Esters ◽  
Convenient Synthesis

Fe(ClO4)3·H2O-Catalyzed Ritter Reaction: A Convenient Synthesis of Amides from Esters and Nitriles

Synlett ◽  
2018 ◽  
Vol 29 (17) ◽  
pp. 2257-2264 ◽  
Author(s):  
Min Ji ◽  
Chengliang Feng ◽  
Bin Yan ◽  
Guibo Yin ◽  
Junqing Chen
Keyword(s):  
Solvent Free ◽  
Ritter Reaction ◽  
Efficient Catalyst ◽  
Tert Butyl ◽  
Butyl Esters ◽  
Convenient Synthesis ◽  
Solvent Free Conditions ◽  
Aryl Nitriles ◽  
The Ritter Reaction

An efficient and inexpensive synthesis of N-substituted amides from the Ritter reaction of nitriles with esters catalyzed by Fe(ClO4)3·H2O is described. Fe(ClO4)3·H2O is an economically efficient catalyst for the Ritter reaction under solvent-free conditions. Reactions of a range of esters (benzyl, sec-alkyl, and tert-butyl esters) with nitriles (primary, secondary, tertiary, and aryl nitriles) were performed to provide the corresponding amides in high to excellent yields.

A convenient synthesis of N -Boc-protected tert -butyl esters of phenylglycines from benzylamines

2001 ◽  
Vol 42 (43) ◽  
pp. 7637-7639 ◽  
Author(s):  
Naoki Kise ◽  
Hiroshi Ozaki ◽  
Hiroaki Terui ◽  
Kengo Ohya ◽  
Nasuo Ueda
Keyword(s):  
Tert Butyl ◽  
Butyl Esters ◽  
Convenient Synthesis

ChemInform Abstract: A Convenient Synthesis of N-Boc-Protected tert-Butyl Esters of Phenylglycines from Benzylamines.

ChemInform ◽  
2010 ◽  
Vol 33 (3) ◽  
pp. no-no
Author(s):  
Naoki Kise ◽  
Hiroshi Ozaki ◽  
Hiroaki Terui ◽  
Kengo Ohya ◽  
Nasuo Ueda
Keyword(s):  
Tert Butyl ◽  
Butyl Esters ◽  
Convenient Synthesis

scholarly journals PCl3-mediated transesterification and aminolysis of tert-butyl esters via acid chloride formation

2021 ◽  
pp. 174751982098753
Author(s):  
Xiaofang Wu ◽  
Lei Zhou ◽  
Fangshao Li ◽  
Jing Xiao
Keyword(s):  
Acid Chloride ◽  
Bioactive Molecules ◽  
Mechanistic Studies ◽  
One Pot ◽  
Tert Butyl ◽  
Butyl Esters

A PCl3-mediated conversion of tert-butyl esters into esters and amides in one-pot under air is developed. This novel protocol is highlighted by the synthesis of skeletons of bioactive molecules and gram-scale reactions. Mechanistic studies revealed that this transformation involves the formation of an acid chloride in situ, which is followed by reactions with alcohols or amines to afford the desired products.

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