ChemInform Abstract: Fluorous Biphasic Catalysis: Complexation of 1,4,7-[C8F17(CH2)3] 3-1,4,7-Triazacyclononane with [M(C8F17 (CH2)2CO2)2] (M: Mn, Co) to Provide Perfluoroheptane-Soluble Catalysts for Alkane and Alkene Functionalization in the Presence of

ChemInform ◽  
2010 ◽  
Vol 29 (7) ◽  
pp. no-no
Author(s):  
J.-M. VINCENT ◽  
A. RABION ◽  
V. K. YACHANDRA ◽  
R. H. FISH
Keyword(s):  
Biphasic Catalysis ◽  
Alkene Functionalization ◽  
Fluorous Biphasic Catalysis

New bis(fluoro-ponytailed) bipyridine ligands for Pd-catalyzed Heck reactions under fluorous biphasic catalysis condition

Tetrahedron ◽  
2007 ◽  
Vol 63 (9) ◽  
pp. 2019-2023 ◽  
Author(s):  
Norman Lu ◽  
Yan-Chou Lin ◽  
Jeng-Yung Chen ◽  
Chi-Wen Fan ◽  
Ling-Kang Liu
Keyword(s):  
Heck Reactions ◽  
Biphasic Catalysis ◽  
Catalysis Condition ◽  
Fluorous Biphasic Catalysis

Ytterbium perfluorooctanesulfonate catalyzed synthesis of acylals from aldehydes and acetic anhydride in a fluorous biphasic system

2006 ◽  
Vol 84 (11) ◽  
pp. 1563-1566 ◽  
Author(s):  
Wen-Bin Yi ◽  
Ya-Qing Yin ◽  
Chun Cai
Keyword(s):  
Acetic Anhydride ◽  
Significant Loss ◽  
Biphasic System ◽  
Efficient Synthesis ◽  
Biphasic Catalysis ◽  
Highly Efficient ◽  
Fluorous Biphasic Catalysis

Ytterbium perfluorooctanesulfonate [Yb(OPf)3] catalyses the highly efficient synthesis of acylals from aldehydes and acetic anhydride in a fluorous biphase system (FBS) composed of toluene and perfluorodecalin. The fluorous phase containing the fluorous catalyst is easily separated and can be reused several times without significant loss of catalytic activity.Key words: acylals, ytterbium perfluorooctanesulfonate, fluorous biphasic catalysis.

Sign in / Sign up

Export Citation Format

Share Document