ChemInform Abstract: Efficient Synthesis of Various Atropisomeric Amides in Optically Pure Forms and Their Application to Asymmetric Reactions.

ChemInform ◽  
2010 ◽  
Vol 31 (10) ◽  
pp. no-no
Author(s):  
Osamu Kitagawa ◽  
Shu-ichi Momose ◽  
Yoshihisa Fushimi ◽  
Takeo Taguchi
Keyword(s):  
Asymmetric Reactions ◽  
Efficient Synthesis ◽  
Optically Pure

Efficient synthesis of various atropisomeric amides in optically pure forms and their application to asymmetric reactions

1999 ◽  
Vol 40 (50) ◽  
pp. 8827-8831 ◽  
Author(s):  
Osamu Kitagawa ◽  
Shu-ichi Momose ◽  
Yoshihisa Fushimi ◽  
Takeo Taguchi
Keyword(s):  
Asymmetric Reactions ◽  
Efficient Synthesis ◽  
Optically Pure

ChemInform Abstract: A General and Efficient Synthesis of Optically Pure S- Arylmercapturates.

ChemInform ◽  
2010 ◽  
Vol 26 (39) ◽  
pp. no-no
Author(s):  
S. NAKAMURA ◽  
M. KONDO ◽  
K. GOTO ◽  
S. NAITO ◽  
Y. TSUDA ◽  
...  
Keyword(s):  
Efficient Synthesis ◽  
Optically Pure

Efficient Synthesis of Optically Pure Nω-Alkylated l-Arginines

Synthesis ◽  
2008 ◽  
Vol 2008 (15) ◽  
pp. 2391-2397 ◽  
Author(s):  
Bernd Clement ◽  
Dennis Schade ◽  
Jürke Kotthaus
Keyword(s):  
Efficient Synthesis ◽  
Optically Pure

Efficient Synthesis of Optically Pure 1,1,1-Trifluoro-2-alkanols through Lipase-Catalyzed Acylation in Organic Media

1996 ◽  
Vol 61 (26) ◽  
pp. 9635-9635
Author(s):  
Hiroki Hamada ◽  
Mizuho Shiromoto ◽  
Makoto Funahashi ◽  
Toshiyuki Itoh ◽  
Kaoru Nakamura
Keyword(s):  
Organic Media ◽  
Efficient Synthesis ◽  
Optically Pure

scholarly journals Highly Efficient Synthesis of Optically Pure (S )-1-phenyl-1,2-ethanediol by a Self-Sufficient Whole Cell Biocatalyst

ChemistryOpen ◽  
2015 ◽  
Vol 4 (4) ◽  
pp. 483-488 ◽  
Author(s):  
Xi Chen ◽  
Ting Mei ◽  
Yunfeng Cui ◽  
Qijia Chen ◽  
Xiangtao Liu ◽  
...  
Keyword(s):  
Efficient Synthesis ◽  
Whole Cell ◽  
Highly Efficient ◽  
Whole Cell Biocatalyst ◽  
Optically Pure

scholarly journals Synthesis of 2-Amino-apopinan-3-ol and Applications of Its Derivatives in Asymmetric Reduction of Ketones

Proceedings ◽  
2019 ◽  
Vol 41 (1) ◽  
pp. 63
Author(s):  
Anna Kmieciak ◽  
Marek P. Krzemiński
Keyword(s):  
Amino Alcohol ◽  
Asymmetric Reduction ◽  
Optically Active ◽  
Asymmetric Reactions ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Active Compounds ◽  
Reduction Methods ◽  
Optically Pure ◽  
Reduction Of Ketones

Monoterpenes are optically active compounds which occur in nature. This fact makes them interesting precursors for the synthesis of optically active ligands, which can be applied in various asymmetric reactions. In this work, we present the synthesis of optically pure 2-amino-apopinan-3-ol from (−)-α-pinene. The obtained amino alcohol was used as a precursor of oxazaborolidine, which was used as catalyst in the asymmetric reduction of aryl-alkyl ketones with borane. In the second part, we transformed 2-amino-apopinan-3-ol into PHOX ligand in a three-step reaction. The complex of ruthenium precursor with PHOX ligand was used as a catalyst in the asymmetric transfer hydrogenation of aryl-alkyl ketones. Alcohols with enantiomeric excesses of up to 97% were isolated using both reduction methods.

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