asymmetric transfer hydrogenation
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Asymmetric hydrogenation and transfer hydrogenation in the enantioselective synthesis of flavonoids

2022 ◽  
Author(s):  
Guilherme S Caleffi ◽  
Felipe C Demidoff ◽  
Carmen Najera ◽  
Paulo Roberto Ribeiro Costa
Keyword(s):  
Asymmetric Hydrogenation ◽  
Enantioselective Synthesis ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Chiral Compounds ◽  
Synthetic Methodologies

Asymmetric hydrogenation (AH) and asymmetric transfer hydrogenation (ATH) are versatile synthetic methodologies widely employed in the preparation of chiral compounds. In this review, we explore the applications of AH and...

Total Synthesis of Resolvin T4

Synlett ◽  
2021 ◽  
Author(s):  
Narihito Ogawa ◽  
Kohei Arai ◽  
Yuichi Kobayashi
Keyword(s):  
Total Synthesis ◽  
Ring Opening ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Ring Opening Reaction ◽  
Propargylic Alcohol ◽  
Chiral Centers ◽  
Wittig Reactions

AbstractA total synthesis of resolvin T4 was achieved by connecting three intermediates by Wittig reactions. The enal in the C1–C10 part was constructed through reduction of a propargylic alcohol with Red-Al followed by oxidation. The enal moiety in the C11–C16 part was synthesized by a ring-opening reaction of a silyl epoxide followed by a Peterson elimination. The chiral centers at C7 and C13 were constructed by ruthenium-catalyzed asymmetric transfer hydrogenation.

Iridium-Catalyzed Asymmetric Transfer Hydrogenation of Quinolines in Biphasic Systems or Water

2021 ◽  
Author(s):  
Lixian Wang ◽  
Jin Lin ◽  
Chungu Xia ◽  
Wei Sun
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Biphasic Systems

Chiral Iridium Complexes of Anionic NCP Pincer Ligand for Asymmetric Transfer Hydrogenation of 1,1-Diarylethenes with Ethanol

2021 ◽  
Author(s):  
Lu Qian ◽  
Xixia Tang ◽  
Zhidao Huang ◽  
Yulei Wang ◽  
Guixia Liu ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Iridium Complexes ◽  
Asymmetric Transfer Hydrogenation ◽  
Pincer Ligand

Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation of β-Substituted α-Oxobutyrolactones

2021 ◽  
Author(s):  
Zi-Qi Hu ◽  
Xiang Li ◽  
Li-Xia Liu ◽  
Chang-Bin Yu ◽  
Yong-Gui Zhou
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation

scholarly journals Asymmetric transfer hydrogenation of heterocycle-containing acetophenone derivatives using N-functionalised [(benzene)Ru(II)(TsDPEN)] complexes

Tetrahedron ◽  
2021 ◽  
pp. 132562
Author(s):  
Jonathan Barrios-Rivera ◽  
Yingjian Xu ◽  
Guy J. Clarkson ◽  
Martin Wills
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Acetophenone Derivatives

scholarly journals Does the Configuration at the Metal Matter in Noyori–Ikariya Type Asymmetric Transfer Hydrogenation Catalysts?

ACS Catalysis ◽  
2021 ◽  
pp. 13649-13659
Author(s):  
Andrew M. R. Hall ◽  
Daniel B. G. Berry ◽  
Jaime N. Crossley ◽  
Anna Codina ◽  
Ian Clegg ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Hydrogenation Catalysts

Asymmetric Transfer Hydrogenation of α-Keto Amides; Highly Enantioselective Formation of Malic Acid Diamides and α-Hydroxyamides

2021 ◽  
Author(s):  
Shweta K. Gediya ◽  
Vijyesh K. Vyas ◽  
Guy J. Clarkson ◽  
Martin Wills
Keyword(s):  
Malic Acid ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation

Diboron-mediated palladium-catalyzed asymmetric transfer hydrogenation using the proton of alcohols as hydrogen source

2021 ◽  
Author(s):  
Bo Wu ◽  
Jimin Yang ◽  
Shu-Bo Hu ◽  
Chang-Bin Yu ◽  
Zi-Biao Zhao ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Palladium Catalyzed
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