Ethyl α-Fluoro Silyl Enol Ether: Stereoselective Synthesis and Its Aldol Reaction with Aldehydes and Ketones.

The reactivity of aldehydes and ketones in asymmetric organo-SOMO reactions with enol silanes was explored. The best results were obtained with 3-phenylpropanal and tetralone-derived silyl enol ether and silyl ketene thioacetal.

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ChemInform Abstract: Catalytic Asymmetric Aldol Reaction of the Silyl Enol Ether of Acetic Acid Thioester with Aldehydes Using Chiral Tin(II) Lewis Acid.

ChemInform ◽

10.1002/chin.199144108 ◽

2010 ◽

Vol 22 (44) ◽

pp. no-no

Author(s):

S. KOBAYASHI ◽

M. FURUYA ◽

A. OHTSUBO ◽

T. MUKAIYAMA

Keyword(s):

Acetic Acid ◽

Lewis Acid ◽

Aldol Reaction ◽

Enol Ether ◽

Asymmetric Aldol ◽

Silyl Enol Ether ◽

Asymmetric Aldol Reaction ◽

Catalytic Asymmetric

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CuCl/Zn-promoted Mukaiyama aldol reaction of phenyl α-fluoro silyl enol ether with aldehydes

Chinese Journal of Chemistry ◽

10.1002/cjoc.20040220916 ◽

2010 ◽

Vol 22 (9) ◽

pp. 953-957 ◽

Cited By ~ 7

Author(s):

Ding-Ying Zhou ◽

Umg-Yun Chen

Keyword(s):

Aldol Reaction ◽

Enol Ether ◽

Mukaiyama Aldol Reaction ◽

Silyl Enol Ether ◽

Mukaiyama Aldol

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Magnesium Bromide Diethyl Etherate Mediated Highly Diastereoselective Aldol Reaction between an Aldehyde and a Silyl Enol Ether

Chemistry Letters ◽

10.1246/cl.2001.190 ◽

2001 ◽

Vol 30 (3) ◽

pp. 190-191 ◽

Cited By ~ 23

Author(s):

Hidehiko Fujisawa ◽

Yasuhiro Sasaki ◽

Teruaki Mukaiyama

Keyword(s):

Aldol Reaction ◽

Magnesium Bromide ◽

Enol Ether ◽

Silyl Enol Ether

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ChemInform Abstract: Asymmetric Synthesis of Functionalized Tertiary Alcohols, e.g. (IV), by Diastereoselective Aldol Reaction of Silyl Enol Ether and Ketene Silyl Acetal (III) with α-Keto Esters (II) Bearing an Optically Active Cyclitol as Chiral Auxilia

ChemInform ◽

10.1002/chin.199501102 ◽

2010 ◽

Vol 26 (1) ◽

pp. no-no

Author(s):

T. AKIYAMA ◽

K. ISHIKAWA ◽

S. OZAKI

Keyword(s):

Asymmetric Synthesis ◽

Aldol Reaction ◽

Optically Active ◽

Enol Ether ◽

Tertiary Alcohols ◽

Keto Esters ◽

Silyl Enol Ether

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Dicationic (BINAP)palladium-catalyzed enantioselective aldol reaction of aldehydes with a silyl enol ether: a simplified practical procedure

Tetrahedron Letters ◽

10.1016/j.tetlet.2006.02.153 ◽

2006 ◽

Vol 47 (23) ◽

pp. 3959-3962 ◽

Cited By ~ 14

Author(s):

Syun-ichi Kiyooka ◽

Satomi Hosokawa ◽

Sayaka Tsukasa

Keyword(s):

Aldol Reaction ◽

Enol Ether ◽

Practical Procedure ◽

Silyl Enol Ether ◽

Palladium Catalyzed

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Highly stereoselective indium trichloride-catalysed asymmetric aldol reaction of formaldehyde and a glucose-derived silyl enol ether in water

Chemical Communications ◽

10.1039/a800486b ◽

1998 ◽

pp. 861-871 ◽

Cited By ~ 27

Author(s):

Teck-Peng Loh ◽

Guan-Leong Chua ◽

Jagadese J. Vittal ◽

Meng-Wah Wong

Keyword(s):

Aldol Reaction ◽

Enol Ether ◽

Asymmetric Aldol ◽

Silyl Enol Ether ◽

Asymmetric Aldol Reaction

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ChemInform Abstract: Magnesium Bromide Diethyl Etherate Mediated Highly Diastereoselective Aldol Reaction Between an Aldehyde and a Silyl Enol Ether.

ChemInform ◽

10.1002/chin.200133107 ◽

2010 ◽

Vol 32 (33) ◽

pp. no-no

Author(s):

Hidehiko Fujisawa ◽

Yasuhiro Sasaki ◽

Teruaki Mukaiyama

Keyword(s):

Aldol Reaction ◽

Magnesium Bromide ◽

Enol Ether ◽

Silyl Enol Ether

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ChemInform Abstract: Highly Stereoselective Indium Trichloride-Catalyzed Asymmetric Aldol Reaction of Formaldehyde and a Glucose-Derived Silyl Enol Ether in Water.

ChemInform ◽

10.1002/chin.199833246 ◽

2010 ◽

Vol 29 (33) ◽

pp. no-no

Author(s):

T.-P. LOH ◽

G.-L. CHUA ◽

J. J. VITTAL ◽

M.-W. WONG

Keyword(s):

Aldol Reaction ◽

Enol Ether ◽

Asymmetric Aldol ◽

Silyl Enol Ether ◽

Asymmetric Aldol Reaction

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