Binuclear and Polynuclear Transition Metal Complexes with Macrocyclic Ligands. Part 3. New Polydentate Macrocyclic Ligands in Reactions of 4-Alkyl-2,6-diformylphenols with 1,2-Diaminobenzenes.

ChemInform ◽  
2004 ◽  
Vol 35 (37) ◽  
Author(s):  
N. E. Borisova ◽  
M. D. Reshetova ◽  
Yu. A. Ustynyuk
2005 ◽  
Vol 54 (9) ◽  
pp. 2219-2223 ◽  
Author(s):  
V. V. Roznyatovsky ◽  
N. E. Borisova ◽  
M. D. Reshetova ◽  
A. G. Buyanovskaya ◽  
Yu. A. Ustynyuk

Author(s):  
Muhammad S. Khan ◽  
Nawal K. Al-Rasbi ◽  
Edwin C. Constable ◽  
Adrian R. Dale ◽  
Jack Lewis

The reaction of the pendant hydroxyethyl group in the planar pentadentate macrocyclic ligand,1,11-bis(2’-hydroxyethyl)-4,8;12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa- 2,4,6,9,12,14,18,20-octaene (L2), derived from the condensation of 2,6-pyridinedialdehyde with 6,6’-bis(2’ hydroxyethylhydrazino) -2,2’-bipyridine (L1), has been investigated. Esterification reactions are facile, and the reaction of the hydroxyethyl-substituted macrocycle with thionyl chloride yields a chloroethyl derivative. Metal complexes of the new derivatized macrocyclic ligands L3-6having general formula ML3-6X2.nH2O (M = Mn, Fe, Co, Ni, Cu, Zn) are readily prepared. 


2000 ◽  
Vol 56 (s1) ◽  
pp. s332-s332
Author(s):  
V. Ch. Kravtsov ◽  
Yu. A. Simonov ◽  
J. Lipkowski ◽  
V. B. Arion ◽  
N. V. Gerbeleu ◽  
...  

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