ChemInform Abstract: Ring Opening of α,β-Epoxy Phenyl Ketones with Ceric Ammonium Nitrate (CAN) and Potassium Bromide.

ChemInform ◽  
2008 ◽  
Vol 39 (33) ◽  
Author(s):  
Zhou Lu ◽  
Wentao Wu ◽  
Lijun Peng ◽  
Longmin Wu
2008 ◽  
Vol 86 (2) ◽  
pp. 142-145 ◽  
Author(s):  
Zhou Lu ◽  
Wentao Wu ◽  
Lijun Peng ◽  
Longmin Wu

Ring-opening reaction of α,β-epoxy phenyl ketones was achieved cooperatively using cerium ammonium nitrate (CAN) and potassium bromide. The reaction occurred regioselectively at the β-C to afford syn-β-bromo-α-hydroxyl ketones as main outcomes.Key words: ring-opening, epoxide, ceric ammonium nitrate, potassium bromide.


ChemInform ◽  
2011 ◽  
Vol 42 (15) ◽  
pp. no-no
Author(s):  
Yugang Chen ◽  
Weijiang Ying ◽  
Michael Harmata

1983 ◽  
Vol 12 (7) ◽  
pp. 1001-1002 ◽  
Author(s):  
Juji Yoshimura ◽  
Masanori Yamaura ◽  
Tsuneji Suzuki ◽  
Hironobu Hashimoto

1985 ◽  
Vol 33 (5) ◽  
pp. 2122-2128 ◽  
Author(s):  
YOSHIYASU KITAHARA ◽  
SHINSUKE NAKAHARA ◽  
RYUICHI NUMATA ◽  
AKINORI KUBO

1992 ◽  
Vol 33 (27) ◽  
pp. 3855-3858 ◽  
Author(s):  
Philippe Cotelle ◽  
Jean-Pierre Catteau

Tetrahedron ◽  
1996 ◽  
Vol 52 (12) ◽  
pp. 4175-4180 ◽  
Author(s):  
Jean-Marc Chapuzet ◽  
Sophie Beauchemin ◽  
Benoit Daoust ◽  
Jean Lessard

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