ChemInform Abstract: Palladium Complexes Containing Multidentate Phenoxy-Pyridyl-Amidate Ligands: Highly Efficient Catalyst for Heck Coupling of Deactivated Aryl Halides.

ChemInform ◽  
2013 ◽  
Vol 44 (23) ◽  
pp. no-no
Author(s):  
M. Lakshmi Kantam ◽  
Manne Annapurna ◽  
Pravin R. Likhar ◽  
P. Srinivas ◽  
Nedaossadat Mirzadeh ◽  
...  
Keyword(s):  
Palladium Complexes ◽  
Aryl Halides ◽  
Heck Coupling ◽  
Efficient Catalyst ◽  
Highly Efficient

Palladium complexes containing multidentate phenoxy–pyridyl–amidate ligands: Highly efficient catalyst for Heck coupling of deactivated aryl halides

2013 ◽  
Vol 723 ◽  
pp. 129-136 ◽  
Author(s):  
M. Lakshmi Kantam ◽  
Manne Annapurna ◽  
Pravin R. Likhar ◽  
P. Srinivas ◽  
Nedaossadat Mirzadeh ◽  
...  
Keyword(s):  
Palladium Complexes ◽  
Aryl Halides ◽  
Heck Coupling ◽  
Efficient Catalyst ◽  
Highly Efficient

A highly efficient catalyst for Suzuki coupling of aryl halides and bromoarylphosphine oxides

2007 ◽  
Vol 48 (11) ◽  
pp. 2025-2027 ◽  
Author(s):  
Mohammad Joshaghani ◽  
Marzieh Daryanavard ◽  
Ezzat Rafiee ◽  
Jianliang Xiao ◽  
Collin Baillie
Keyword(s):  
Suzuki Coupling ◽  
Aryl Halides ◽  
Efficient Catalyst ◽  
Highly Efficient

ChemInform Abstract: CuS/Fe: A Novel and Highly Efficient Catalyst System for Coupling Reaction of Aryl Halides with Diaryl Diselenides.

ChemInform ◽  
2011 ◽  
Vol 42 (8) ◽  
pp. no-no
Author(s):  
Yaming Li ◽  
Huifeng Wang ◽  
Xiaoying Li ◽  
Tao Chen ◽  
Defeng Zhao
Keyword(s):  
Coupling Reaction ◽  
Catalyst System ◽  
Aryl Halides ◽  
Efficient Catalyst ◽  
Highly Efficient

A Highly Efficient Catalyst for Suzuki Coupling of Aryl Halides and Bromoarylphosphine Oxides.

ChemInform ◽  
2007 ◽  
Vol 38 (26) ◽  
Author(s):  
Mohammad Joshaghani ◽  
Marzieh Daryanavard ◽  
Ezzat Rafiee ◽  
Jianliang Xiao ◽  
Collin Baillie
Keyword(s):  
Suzuki Coupling ◽  
Aryl Halides ◽  
Efficient Catalyst ◽  
Highly Efficient

scholarly journals Facile Synthesis and Characterization of Palladium@Carbon Catalyst for the Suzuki-Miyaura and Mizoroki-Heck Coupling Reactions

2021 ◽  
Vol 11 (11) ◽  
pp. 4822
Author(s):  
Hamed M. Alshammari ◽  
Obaid F. Aldosari ◽  
Mohammad Hayal Alotaibi ◽  
Raja L. Alotaibi ◽  
Mosaed S. Alhumaimess ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Activated Carbon ◽  
Coupling Reaction ◽  
Aryl Halides ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Heck Coupling ◽  
Efficient Catalyst ◽  
X Ray ◽  
Suzuki Reactions

Palladium-based carbon catalysts (Pd/C) can be potentially applied as an efficient catalyst for Suzuki–Miyaura and Mizoroki–Heck coupling reactions. Herein, a variety of catalysts of palladium on activated carbon were prepared by varying the content of ‘Pd’ via an in situ reduction method, using hydrogen as a reducing agent. The as-prepared catalysts (0.5 wt % Pd/C, 1 wt % Pd/C, 2 wt % Pd/C and 3 wt % Pd/C) were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and Brunauer–Emmett–Teller (BET) analyses. The catalysts were tested as a coupling catalyst for Suzuki–Miyaura coupling reactions involving aryl halides and phenyl boronic acid. The optimization of the catalyst by varying the palladium content on the activated carbon yielded Pd/C catalysts with very high catalytic activity for Suzuki reactions of aryl halides and a Mizoroki–Heck cross-coupling reaction of 4-bromoanisol and acrylic acid in an aqueous medium. A high ‘Pd’ content and uniform ‘Pd’ impregnation significantly affected the activity of the catalysts. The catalytic activity of 3% Pd/C was found to make it a more efficient catalyst when compared with the other synthesized Pd/C catalysts. Furthermore, the catalyst reusability was also tested for Suzuki reactions by repeatedly performing the same reaction using the recovered catalyst. The 3% Pd/C catalyst displayed better reusability even after several reactions.

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