ChemInform Abstract: Organic Base-Promoted Enantioselective Electrophilic Cyanation of β-Keto Esters by Using Chiral Phase-Transfer Catalysts.

ChemInform ◽  
2016 ◽  
Vol 47 (2) ◽  
Author(s):  
Min Chen ◽  
Zhi-Tang Huang ◽  
Qi-Yu Zheng
Keyword(s):  
Phase Transfer ◽  
Organic Base ◽  
Chiral Phase ◽  
Phase Transfer Catalysts ◽  
Keto Esters ◽  
Chiral Phase Transfer Catalysts

Organic base-promoted enantioselective electrophilic cyanation of β-keto esters by using chiral phase-transfer catalysts

2015 ◽  
Vol 13 (33) ◽  
pp. 8812-8816 ◽  
Author(s):  
Min Chen ◽  
Zhi-Tang Huang ◽  
Qi-Yu Zheng
Keyword(s):  
Phase Transfer ◽  
Cinchona Alkaloid ◽  
Hypervalent Iodine ◽  
Organic Base ◽  
Chiral Phase ◽  
Phase Transfer Catalysts ◽  
Keto Esters ◽  
Chiral Phase Transfer Catalysts

Highly enantioselective electrophilic cyanation of β-keto esters with hypervalent iodine(iii) as the cyanating reagent induced by cinchona alkaloid-based chiral phase-transfer catalysts using an organic base is reported.

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