ChemInform Abstract: Iridium(III)-Catalyzed Direct Arylation of C-H Bonds with Diaryliodonium Salts.

ChemInform ◽  
2016 ◽  
Vol 47 (9) ◽  
pp. no-no
Author(s):  
Pan Gao ◽  
Wei Guo ◽  
Jingjing Xue ◽  
Yue Zhao ◽  
Yu Yuan ◽  
...  
Keyword(s):  
Direct Arylation ◽  
Diaryliodonium Salts

Potassium tert-Butoxide Mediated Arylation of 2-Substituted Malononitriles Using Diaryliodonium Salts

Synlett ◽  
2017 ◽  
Vol 28 (16) ◽  
pp. 2139-2142 ◽  
Author(s):  
Jianwei Han ◽  
Limin Wang ◽  
Xiaofei Qian ◽  
Bowen Xu
Keyword(s):  
Transition Metal ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Synthetic Method ◽  
Direct Arylation ◽  
Diaryliodonium Salts

Direct arylation of 2-substituted malononitriles using diaryliodonium salts without involving transition-metal catalysts was developed. By using potassium tert-butoxide as a promoter, the desired 2-substituated α-arylmalononitriles derivatives were synthesized in good to excellent yields of 55–96%. This synthetic method provided an efficient way to prepare a variety of 2-substituted arylmalononitriles which were useful in agrochemicals.

scholarly journals Cu-Catalyzed Direct Arylation of Benzothiazoles with Diaryliodonium Salts

2020 ◽  
Vol 40 (8) ◽  
pp. 2476 ◽  
Author(s):  
Huaigui Li ◽  
Peng Yang ◽  
Zheng Xu ◽  
Zhengyin Du ◽  
Ying Fu
Keyword(s):  
Direct Arylation ◽  
Diaryliodonium Salts

ChemInform Abstract: Copper-Catalyzed Direct Arylation of Cyclic Enamides Using Diaryliodonium Salts.

ChemInform ◽  
2013 ◽  
Vol 44 (22) ◽  
pp. no-no
Author(s):  
Nicolas Gigant ◽  
Laetitia Chausset-Boissarie ◽  
Marie-Charlotte Belhomme ◽  
Thomas Poisson ◽  
Xavier Pannecoucke ◽  
...  
Keyword(s):  
Direct Arylation ◽  
Diaryliodonium Salts

Copper-Catalyzed Direct Arylation of Cyclic Enamides Using Diaryliodonium Salts

2012 ◽  
Vol 15 (2) ◽  
pp. 278-281 ◽  
Author(s):  
Nicolas Gigant ◽  
Laëtitia Chausset-Boissarie ◽  
Marie-Charlotte Belhomme ◽  
Thomas Poisson ◽  
Xavier Pannecoucke ◽  
...  
Keyword(s):  
Direct Arylation ◽  
Diaryliodonium Salts

Iridium(III)-Catalyzed Direct Arylation of C–H Bonds with Diaryliodonium Salts

2015 ◽  
Vol 137 (38) ◽  
pp. 12231-12240 ◽  
Author(s):  
Pan Gao ◽  
Wei Guo ◽  
Jingjing Xue ◽  
Yue Zhao ◽  
Yu Yuan ◽  
...  
Keyword(s):  
Direct Arylation ◽  
Diaryliodonium Salts

scholarly journals Recent Advances in Transition-Metal-Free Late-Stage C-H and N-H Arylation of Heteroarenes Using Diaryliodonium Salts

2021 ◽  
Vol 14 (7) ◽  
pp. 661
Author(s):  
Thierry Besson ◽  
Corinne Fruit
Keyword(s):  
Transition Metal ◽  
Late Stage ◽  
Heterocyclic Compounds ◽  
Environmentally Friendly ◽  
Direct Arylation ◽  
Stepping Stone ◽  
Metal Free ◽  
Bond Forming ◽  
Diaryliodonium Salts ◽  
Recent Advances

Transition-metal-free direct arylation of C-H or N-H bonds is one of the key emerging methodologies that is currently attracting tremendous attention. Diaryliodonium salts serve as a stepping stone on the way to alternative environmentally friendly and straightforward pathways for the construction of C-C and C-heteroatom bonds. In this review, we emphasize the recent synthetic advances of late-stage C(sp2)-N and C(sp2)-C(sp2) bond-forming reactions under metal-free conditions using diaryliodonium salts as arylating reagent and its applications to the synthesis of new arylated bioactive heterocyclic compounds.

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