Kinetic Isotope Effect as a Tool To Investigate the Oxygen Reduction Reaction on Pt‐based Electrocatalysts – Part II: Effect of Platinum Dispersion

ChemPhysChem ◽  
2020 ◽  
Vol 21 (12) ◽  
pp. 1331-1339 ◽  
Author(s):  
Morteza Rezaei Talarposhti ◽  
Tristan Asset ◽  
Samuel T. Garcia ◽  
Yechuan Chen ◽  
Sergio Herrera ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Isotope Effect ◽  
Kinetic Isotope Effect ◽  
Reduction Reaction ◽  
Kinetic Isotope ◽  
Platinum Dispersion

scholarly journals [RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

2018 ◽  
Vol 54 (61) ◽  
pp. 8518-8521 ◽  
Author(s):  
T. W. Schneider ◽  
M. T. Hren ◽  
M. Z. Ertem ◽  
A. M. Angeles-Boza
Keyword(s):  
Carbon Dioxide ◽  
Dft Calculations ◽  
Isotope Effect ◽  
Kinetic Isotope Effect ◽  
Ruthenium Complex ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Reduction Reaction ◽  
Kinetic Isotope

13C kinetic isotope effect determinations combined with DFT calculations provide insight on the CO2 reduction reaction catalyzed by a ruthenium complex.

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