Characterization of “Cd10S4(SPh)12”, the Thermal Decomposition Product of (NMe4)4[Cd10S4(SPh)16]: Synthesis of a Neutral Cd54 Sulfide Cluster and of a Polymeric Chain of Thiolate-Bridged Cd17 Sulfide Clusters

2010 ◽  
Vol 2010 (21) ◽  
pp. 3299-3306 ◽  
Author(s):  
Maria Bendova ◽  
Michael Puchberger ◽  
Ulrich Schubert
Keyword(s):  
Thermal Decomposition ◽  
Decomposition Product ◽  
Polymeric Chain ◽  
Thermal Decomposition Product ◽  
Sulfide Clusters ◽  
Sulfide Cluster

scholarly journals Thermal Decomposition of the HXeCl···H2O Complex in Solid Xenon: Experimental Characterization of the Two-body Decomposition Channel

2019 ◽  
Author(s):  
Masashi Tsuge ◽  
Markku Räsänen ◽  
Leonid Khriachtchev
Keyword(s):  
Activation Energy ◽  
Thermal Decomposition ◽  
Water Molecule ◽  
Decomposition Product ◽  
Decomposition Process ◽  
Experimental Characterization ◽  
Thermal Decomposition Product ◽  
Thermal Decomposition Process ◽  
Theoretical Predictions

The thermal decomposition process of HXeCl···H2O in solid Xe is studied, and HCl···H2O is identified as a decomposition product. The production is due to the two-body (2B) decomposition of HXeCl moiety, in agreement with theoretical predictions. Two types of 2B decomposition paths are predicted: catalytic and unimolecular 2B decompositions, where water molecule plays different roles. In an experiment to selectively produce HXeCl···D2O, only HCl···D2O is observed as a thermal decomposition product, indicating the occurrence of unimolecular 2B decomposition, where water molecule serves as a spectator. The activation energy for this decomposition process is experimentally determined to be 15 kJ mol−1.<br>

scholarly journals Thermal Decomposition of the HXeCl···H2O Complex in Solid Xenon: Experimental Characterization of the Two-body Decomposition Channel

2019 ◽  
Author(s):  
Masashi Tsuge ◽  
Markku Räsänen ◽  
Leonid Khriachtchev
Keyword(s):  
Activation Energy ◽  
Thermal Decomposition ◽  
Water Molecule ◽  
Decomposition Product ◽  
Decomposition Process ◽  
Experimental Characterization ◽  
Thermal Decomposition Product ◽  
Thermal Decomposition Process ◽  
Theoretical Predictions

The thermal decomposition process of HXeCl···H2O in solid Xe is studied, and HCl···H2O is identified as a decomposition product. The production is due to the two-body (2B) decomposition of HXeCl moiety, in agreement with theoretical predictions. Two types of 2B decomposition paths are predicted: catalytic and unimolecular 2B decompositions, where water molecule plays different roles. In an experiment to selectively produce HXeCl···D2O, only HCl···D2O is observed as a thermal decomposition product, indicating the occurrence of unimolecular 2B decomposition, where water molecule serves as a spectator. The activation energy for this decomposition process is experimentally determined to be 15 kJ mol−1.<br>

Thermal analysis of prednicarbate and characterization of thermal decomposition product

2009 ◽  
Vol 102 (1) ◽  
pp. 277-283 ◽  
Author(s):  
Hélio Salvio Neto ◽  
Fábio Alessandro Proença Barros ◽  
Flávio Machado de Sousa Carvalho ◽  
Jivaldo Rosário Matos
Keyword(s):  
Thermal Analysis ◽  
Thermal Decomposition ◽  
Decomposition Product ◽  
Thermal Decomposition Product

Electrocatalytic water oxidation reaction promoted by cobalt-Prussian blue and its thermal decomposition product under mild conditions

2020 ◽  
Vol 49 (45) ◽  
pp. 16488-16497
Author(s):  
Priscilla J. Zambiazi ◽  
Gabriel de O. Aparecido ◽  
Thiago V. de B. Ferraz ◽  
William S. J. Skinner ◽  
Rafael G. Yoshimura ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Prussian Blue ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Decomposition Product ◽  
Thermal Decomposition Product ◽  
Mild Conditions ◽  
Mount Fuji

Water oxidation studies with Co-Prussian blue and Co3O4. Figure adapted from ‘Under the Wave off Kanagawa’ (Kanagawa oki nami ura), also known as ‘The Great Wave’, from the series ‘Thirty-six Views of Mount Fuji’ (‘Fugaku sanjūrokkei’) by K. Hokusai.

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