Structural Variety of Iron Carbonyl Clusters Featuring Ferrocenylphosphines

2021 ◽  
Author(s):  
Marcus Korb ◽  
Xianming Liu ◽  
Sebastian Walz ◽  
Julia Mahrholdt ◽  
Alexey A. Popov ◽  
...  
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Clusters ◽  
Structural Variety

Synthesis and reactivity of iron carbonyl clusters containing alkynethiolate ligands

2005 ◽  
Vol 358 (5) ◽  
pp. 1521-1530 ◽  
Author(s):  
Alberto Cabrera ◽  
Esther Delgado ◽  
Cesar Pastor ◽  
Miguel A. Maestro ◽  
Félix Zamora
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Clusters

Ruthenium and Iron Carbonyl Clusters Catalyzed Reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl)benzamide

2011 ◽  
Vol 396-398 ◽  
pp. 2485-2488
Author(s):  
Bao Hua Zhu ◽  
Guo Hua Xu ◽  
Zhi Wei Xia
Keyword(s):  
Ir Spectroscopy ◽  
Elemental Analysis ◽  
Iron Carbonyl ◽  
Carbonyl Cluster ◽  
Carbonyl Clusters ◽  
Excellent Yield ◽  
Ruthenium Carbonyl ◽  
Vis Spectroscopy

One new Ruthenium and one known Iron bimetallic carbonyl clusters containing triphos (1,1,1-tris(diphenylphosphinomethyl)ethane) ligand have been prepared as catalyst to study the reduction of amide to amine. All clusters were characterized by elemental analysis, 1HNMR, 31PNMR and IR spectroscopy. The reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl) benzamide catalyzed by Ru and Fe carbonyl clusters were investigated at 100 ~ 110 °C for 24 ~ 28h, polymethylhydrogensiloxane (PMHS) as reduction agent. The products were analysized using GC-MS, IR and UV-vis spectroscopy and an excellent yield (97%) of N,N-diethyl- (3-methyl)benzamine was obtained when using 3 mol% of bimetallic ruthenium carbonyl cluster as catalyst. The data of IR and UV-vis show that the frameworks of clusters are not changed remarkably during the reaction.

scholarly journals Electron Transfer Mediated by Iron Carbonyl Clusters Enhance Light‐Driven Hydrogen Evolution in Water by Quantum Dots

ChemSusChem ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 3252-3260
Author(s):  
Chuanshuai Li ◽  
Ahibur Rahaman ◽  
Weihua Lin ◽  
Hassan Mourad ◽  
Jie Meng ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Electron Transfer ◽  
Hydrogen Evolution ◽  
Iron Carbonyl ◽  
Carbonyl Clusters

scholarly journals Structures, Interconversions, and Spectroscopy of Iron Carbonyl Clusters with an Interstitial Carbide: Localized Metal Center Reduction by Overall Cluster Oxidation

2017 ◽  
Vol 56 (13) ◽  
pp. 7575-7575
Author(s):  
Subramaniam Kuppuswamy ◽  
Joshua D. Wofford ◽  
Chris Joseph ◽  
Zhu-Lin Xie ◽  
Azim K. Ali ◽  
...  
Keyword(s):  
Iron Carbonyl ◽  
Metal Center ◽  
Carbonyl Clusters ◽  
Interstitial Carbide

REACTION OF BENZYLIC AND ALLYLIC HALIDES WITH IRON-CARBONYL CLUSTERS

1978 ◽  
Vol 7 (12) ◽  
pp. 1309-1312 ◽  
Author(s):  
Saburo Nakanishi ◽  
Toshio Oda ◽  
Tatsuo Ueda ◽  
Yoshio Otsuji
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Clusters ◽  
Allylic Halides

scholarly journals CO-free, aqueous mediated, instant and selective reduction of nitrobenzene via robustly stable chalcogen stabilised iron carbonyl clusters (Fe3E2(CO)9, E = S, Se, Te)

RSC Advances ◽  
2020 ◽  
Vol 10 (54) ◽  
pp. 32516-32521
Author(s):  
Charu Sharma ◽  
Avinash Kumar Srivastava ◽  
Aditi Soni ◽  
Sangeeta Kumari ◽  
Raj Kumar Joshi
Keyword(s):  
Selective Reduction ◽  
Iron Carbonyl ◽  
Carbonyl Clusters ◽  
Feasible Method ◽  
Iron Chalcogenide

In this study, a strongly feasible method for the reduction of nitrobenzene has been developed through highly stable and thermally robust iron chalcogenide carbonyl clusters Fe3E2(CO)9 (E = S, Se or Te).

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