Tin–iron carbonyl clusters from the reaction of stannane, SnH4, with Fe2(CO)9; the crystal structure of SnFe5(CO)19

1989 ◽  
Vol 372 (1) ◽  
pp. 25-32 ◽  
Author(s):  
Skelten G. Anema ◽  
Kenneth M. Mackay ◽  
Brian K. Nicholson
Keyword(s):  
Crystal Structure ◽  
Iron Carbonyl ◽  
Carbonyl Clusters

Synthesis of bimetallic iron-nickel carbonyl clusters: crystal structure of the iron-nickel carbonyl cluster [N(CH3)3CH2Ph][Fe3Ni(CO)8(.mu.-CO)4(.mu.3-H)]

1984 ◽  
Vol 23 (10) ◽  
pp. 1363-1368 ◽  
Author(s):  
Allesandro Ceriotti ◽  
Paolo Chini ◽  
Allesandro Fumagalli ◽  
Thomas F. Koetzle ◽  
Giuliano Longoni ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Carbonyl Cluster ◽  
Carbonyl Clusters ◽  
Nickel Carbonyl ◽  
Iron Nickel

Synthesis and reactivity of iron carbonyl clusters containing alkynethiolate ligands

2005 ◽  
Vol 358 (5) ◽  
pp. 1521-1530 ◽  
Author(s):  
Alberto Cabrera ◽  
Esther Delgado ◽  
Cesar Pastor ◽  
Miguel A. Maestro ◽  
Félix Zamora
Keyword(s):  
Iron Carbonyl ◽  
Carbonyl Clusters

Iron carbonyl complexes of cithiocarbonates. X-ray crystal structure of Fe4(CO)12S(SCH2C5H4FeC5H5)(SCH3)

1981 ◽  
Vol 210 (1) ◽  
pp. C1-C4 ◽  
Author(s):  
Henri Patin ◽  
Gerard Mignani ◽  
Christian Mahe ◽  
Jean-Yves Le Marouille ◽  
Alain Benoit ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Iron Carbonyl ◽  
Carbonyl Complexes ◽  
X Ray

Substitution chemistry of pentaosmium carbonyl clusters: crystal structure of H2Os5(CO)13P(OMe)3PEt3

1990 ◽  
Vol 385 (3) ◽  
pp. 387-398 ◽  
Author(s):  
Brian F.G. Johnson ◽  
Rajesh Khattar ◽  
Jack Lewis ◽  
Paul R. Raithby ◽  
Maria J. Rosales
Keyword(s):  
Crystal Structure ◽  
Carbonyl Clusters ◽  
Substitution Chemistry

Ruthenium and Iron Carbonyl Clusters Catalyzed Reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl)benzamide

2011 ◽  
Vol 396-398 ◽  
pp. 2485-2488
Author(s):  
Bao Hua Zhu ◽  
Guo Hua Xu ◽  
Zhi Wei Xia
Keyword(s):  
Ir Spectroscopy ◽  
Elemental Analysis ◽  
Iron Carbonyl ◽  
Carbonyl Cluster ◽  
Carbonyl Clusters ◽  
Excellent Yield ◽  
Ruthenium Carbonyl ◽  
Vis Spectroscopy

One new Ruthenium and one known Iron bimetallic carbonyl clusters containing triphos (1,1,1-tris(diphenylphosphinomethyl)ethane) ligand have been prepared as catalyst to study the reduction of amide to amine. All clusters were characterized by elemental analysis, 1HNMR, 31PNMR and IR spectroscopy. The reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl) benzamide catalyzed by Ru and Fe carbonyl clusters were investigated at 100 ~ 110 °C for 24 ~ 28h, polymethylhydrogensiloxane (PMHS) as reduction agent. The products were analysized using GC-MS, IR and UV-vis spectroscopy and an excellent yield (97%) of N,N-diethyl- (3-methyl)benzamine was obtained when using 3 mol% of bimetallic ruthenium carbonyl cluster as catalyst. The data of IR and UV-vis show that the frameworks of clusters are not changed remarkably during the reaction.

scholarly journals Electron Transfer Mediated by Iron Carbonyl Clusters Enhance Light‐Driven Hydrogen Evolution in Water by Quantum Dots

ChemSusChem ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 3252-3260
Author(s):  
Chuanshuai Li ◽  
Ahibur Rahaman ◽  
Weihua Lin ◽  
Hassan Mourad ◽  
Jie Meng ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Electron Transfer ◽  
Hydrogen Evolution ◽  
Iron Carbonyl ◽  
Carbonyl Clusters

High nuclearity carbonyl clusters of rhodium. Synthesis and crystal structure of (NMe4)3[Rh14H(CO)25] · Me2CO

1989 ◽  
Vol 363 (1-2) ◽  
pp. 181-188 ◽  
Author(s):  
Gianfranco Ciani ◽  
Massimo Moret ◽  
Angelo Sironi ◽  
Secondo Martinengo
Keyword(s):  
Crystal Structure ◽  
Carbonyl Clusters ◽  
Synthesis And Crystal Structure
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