Selective Bromination of β ‐Positions of Porphyrin by Self‐Catalytic Behaviour of VOTPP: Facile Synthesis, Electrochemical Redox Properties and Catalytic Application

2021 ◽  
Vol 2021 (17) ◽  
pp. 1685-1694
Author(s):  
Mannar R. Maurya ◽  
Ved Prakash ◽  
Fernando Avecilla ◽  
Muniappan Sankar
2021 ◽  
Vol MA2021-01 (16) ◽  
pp. 740-740
Author(s):  
Sandeep Kumar ◽  
Inderpal Yadav ◽  
Renu Kumari Rohal ◽  
Amir Sohel Bulbul ◽  
Muniappan Sankar

2019 ◽  
Vol 48 (40) ◽  
pp. 15002-15011 ◽  
Author(s):  
Pinki Rathi ◽  
Ray Butcher ◽  
Muniappan Sankar

β-Octasubstituted porphyrins having three different substituents (Ph, Br and NO2) have been synthesized. They exhibited highly red-shifted absorption spectral features with tunable redox properties leading to a very low HOMO–LUMO gap as compared to MTPPs.


2009 ◽  
Vol 133 (1-2) ◽  
pp. 1-7 ◽  
Author(s):  
Kuan Soo Shin ◽  
Jeong-Yong Choi ◽  
Chan Seok Park ◽  
Hee Jin Jang ◽  
Kwan Kim

2011 ◽  
Vol 15 (09n10) ◽  
pp. 883-889 ◽  
Author(s):  
P. Bhyrappa ◽  
V. Velkannan

A series of 2,3,12,13-tetrabromo-5,10,15,20-tetrakis(4′-substituted phenyl)porphyrins, H2 T(4′-R Ph) PBr4 ( R = OCH3 , t-butyl, H and CO2CH3 ) and their metal ( Co(II) , Cu(II) , and Zn(II) ) complexes were synthesized and their electrochemical redox properties were explored. The plot of E1/2vs. the Hammett parameter (σp) of the substituents (R) follow a fairly linear relationship for the ring centered redox potentials.


2015 ◽  
Vol 58 (3) ◽  
pp. 467-472 ◽  
Author(s):  
Ji Xiang ◽  
Hanbao Chong ◽  
Jia Tang ◽  
Li Feng ◽  
Bin Zhou ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document