Facile Synthesis of Antipodal β-Arylaminodibromoporphyrins through Buchwald-Hartwig C-N coupling reaction and Exploring Their Spectral and Intriguing Electrochemical Redox Properties

2021 ◽  
pp. 122114
Author(s):  
Kamal Prakash ◽  
W. Ryan Osterloh ◽  
Pinki Rathi ◽  
Karl M. Kadish ◽  
Muniappan Sankar
Keyword(s):  
Coupling Reaction ◽  
Redox Properties ◽  
Facile Synthesis ◽  
Electrochemical Redox

Facile Synthesis, Spectral, and Electrochemical Redox Properties of π-Extended ‘Push-Pull’ Corroles, Porphyrins and Chlorins

2021 ◽  
Vol MA2021-01 (16) ◽  
pp. 740-740
Author(s):  
Sandeep Kumar ◽  
Inderpal Yadav ◽  
Renu Kumari Rohal ◽  
Amir Sohel Bulbul ◽  
Muniappan Sankar
Keyword(s):  
Redox Properties ◽  
Facile Synthesis ◽  
Electrochemical Redox

Unsymmetrical nonplanar ‘push–pull’ β-octasubstituted porphyrins: facile synthesis, structural, photophysical and electrochemical redox properties

2019 ◽  
Vol 48 (40) ◽  
pp. 15002-15011 ◽  
Author(s):  
Pinki Rathi ◽  
Ray Butcher ◽  
Muniappan Sankar
Keyword(s):  
Redox Properties ◽  
Spectral Features ◽  
Facile Synthesis ◽  
Electrochemical Redox ◽  
Homo Lumo

β-Octasubstituted porphyrins having three different substituents (Ph, Br and NO2) have been synthesized. They exhibited highly red-shifted absorption spectral features with tunable redox properties leading to a very low HOMO–LUMO gap as compared to MTPPs.

Suzuki-Miyaura cross-coupling reaction in water: facile synthesis of (hetero) aryl uracil bases using potassiumorganotrifluoroborates under microwave irradiation.

2016 ◽  
Vol 1 (15) ◽  
pp. 4721-4725 ◽  
Author(s):  
Bhaskaran Savitha ◽  
Ayyiliath M. Sajith ◽  
Eeda Koti Reddy ◽  
C. S. Ananda Kumar ◽  
M. Syed Ali Padusha
Keyword(s):  
Microwave Irradiation ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Facile Synthesis ◽  
Cross Coupling Reaction ◽  
Reaction In Water
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