Synthesis of 3‐Acyl‐Isoxazoles
            via
            Radical 5‐
            endo trig
            Cyclization of β,γ‐Unsaturated Ketones with NaNO
            2

Ping Jiang; Yaming Wang; Dengfeng Chen; Yu Zheng; Shenlin Huang

doi:10.1002/ejoc.202101411

Synthesis of 3‐Acyl‐Isoxazoles via Radical 5‐ endo trig Cyclization of β,γ‐Unsaturated Ketones with NaNO 2

European Journal of Organic Chemistry ◽

10.1002/ejoc.202101411 ◽

2022 ◽

Vol 2022 (2) ◽

Author(s):

Ping Jiang ◽

Yaming Wang ◽

Dengfeng Chen ◽

Yu Zheng ◽

Shenlin Huang

Keyword(s):

Unsaturated Ketones

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1,4-Reductions of α,β-Unsaturated Ketones and Aldehydes via in situ Generated Hydridocuprates

Synlett ◽

10.1055/s-1989-20359 ◽

1989 ◽

Vol 1989 (01) ◽

pp. 64-66 ◽

Cited By ~ 2

Author(s):

Bruce H. Lipshutz ◽

Christopher S. Ung ◽

Saumitra Sengupta

Keyword(s):

Unsaturated Ketones

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Silicon Assisted Halogenation I: A Convenient Synthesis of β-chloroketones via Reaction of α,β-unsaturated ketones with Tetrachlorosilane-Phenol

10.3390/ecsoc-13-00181 ◽

2009 ◽

Author(s):

Tarek Salama ◽

Saad Elmorsy

Keyword(s):

Unsaturated Ketones ◽

Convenient Synthesis

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Palladium-Catalyzed Three-Component Coupling Reaction of Benzyl Chlorides, Allyltributylstannane, and Carbon Monoxide: Efficient Synthesis of α,β-Unsaturated Ketones

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) ◽

10.3724/sp.j.1088.2012.10930 ◽

2013 ◽

Vol 33 (3) ◽

pp. 523-529

Author(s):

Xin ZHANG ◽

Xiujuan FENG ◽

Hesong LIU ◽

Yuhu QIN ◽

Yao DAI

Keyword(s):

Carbon Monoxide ◽

Coupling Reaction ◽

Efficient Synthesis ◽

Unsaturated Ketones ◽

Benzyl Chlorides ◽

Palladium Catalyzed ◽

Three Component Coupling

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ChemInform Abstract: ORGANIC PHOTOCHEMISTRY. 53. PHOTOCHEMISTRY OF BICYCLIC Δ-THIA-α,β-UNSATURATED KETONES. A VINYLKETENE MECHANISM

Chemischer Informationsdienst ◽

10.1002/chin.198211122 ◽

1982 ◽

Vol 13 (11) ◽

Author(s):

T. MIYASHI ◽

N. SUTO ◽

T. YAMAKI ◽

T. MUKAI

Keyword(s):

Unsaturated Ketones ◽

Organic Photochemistry

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ChemInform Abstract: Palladium(0)-Catalyzed Reactions of Allylic Benzotriazoles with Enamines: A Novel Method for the Stereoselective Synthesis of (4E)-γ,δ-Unsaturated Ketones.

ChemInform ◽

10.1002/chin.200007039 ◽

2010 ◽

Vol 31 (7) ◽

pp. no-no

Author(s):

Alan R. Katritzky ◽

Zhizhen Huang ◽

Yunfeng Fang

Keyword(s):

Stereoselective Synthesis ◽

Unsaturated Ketones ◽

Novel Method ◽

Catalyzed Reactions

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ChemInform Abstract: Tandem Synthesis of Polysubstituted Pyridines via the Indium(III)-Triflate-Catalyzed Cycloaddition/Oxidative Aromatization of Blaise Reaction Intermediates with α,β-Unsaturated Ketones.

ChemInform ◽

10.1002/chin.201513225 ◽

2015 ◽

Vol 46 (13) ◽

pp. no-no

Author(s):

Zi Xuan ◽

Kris Rathwell ◽

Sang-gi Lee

Keyword(s):

Reaction Intermediates ◽

Unsaturated Ketones ◽

Oxidative Aromatization ◽

Tandem Synthesis

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Divergent Functionalization of α,β-Enones: Catalyst-free Access to β-Azido Ketones and β-Amino α-Diazo Ketones

Chemical Communications ◽

10.1039/d1cc00985k ◽

2021 ◽

Author(s):

Youshao Tu ◽

honglin Dong ◽

Huamin Wang ◽

Yuhui Ao ◽

Yu Liu

Keyword(s):

Carbonyl Compounds ◽

Practical Method ◽

Free Access ◽

Unsaturated Ketones ◽

Catalyst Free

A simple and practical method for the azidation of β-fluoroalkyl α,β-unsaturated ketones to access a wide variety of fluorinated nitrogenous carbonyl compounds is developed. Different from existing precedents, neither metallic...

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Eco-friendly and regioselective synthesis of 3-(isoxazol-5)-yl) indoles from β-ethylthio-β-indolyl-α, β-unsaturated ketones in water

Synthetic Communications ◽

10.1080/00397911.2021.1894339 ◽

2021 ◽

pp. 1-7

Author(s):

Jia Jia ◽

Ye Su ◽

Hai-Feng Yu ◽

Hai-Tao Du ◽

Ze-Min Mei

Keyword(s):

Regioselective Synthesis ◽

Unsaturated Ketones

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ChemInform Abstract: THE CHEMISTRY OF Γ-OXOSULFONES. 1. A NOVEL REARRANGEMENT AND A METHOD FOR THE β-ALKYLATION OF α,β-UNSATURATED KETONES

Chemischer Informationsdienst ◽

10.1002/chin.197733103 ◽

1977 ◽

Vol 8 (33) ◽

pp. no-no

Author(s):

J. FAYOS ◽

J. CLARDY ◽

L. J. DOLBY ◽

T. FARNHAM

Keyword(s):

Unsaturated Ketones

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On the optical activity of α,β-unsaturated ketones

Tetrahedron ◽

10.1016/s0040-4020(01)96311-2 ◽

1968 ◽

Vol 24 (17) ◽

pp. 5803-5816 ◽

Cited By ~ 18

Author(s):

H. Ziffer ◽

C.H. Robinson

Keyword(s):

Optical Activity ◽

Unsaturated Ketones

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