Pheromone Synthesis, CLIV. Synthesis of the Stereoisomers of 3-Methyl-4-octanol to Determine the Absolute Configuration of the Naturally Occurring (3S,4S)-Isomer Isolated as the Male-produced Aggregation Pheromone of the African Palm Weevil,Rhynchophorus phoenicis

1993 ◽  
Vol 1993 (8) ◽  
pp. 865-870 ◽  
Author(s):  
Kenji Mori ◽  
Hiromasa Kiyota ◽  
Didier Rochat
ChemInform ◽  
2009 ◽  
Vol 40 (47) ◽  
Author(s):  
Yujiro Hayashi ◽  
Kuppusamy Sankar ◽  
Hayato Ishikawa ◽  
Yuriko Nozawa ◽  
Kazutoshi Mizoue ◽  
...  

Synlett ◽  
2020 ◽  
Vol 31 (16) ◽  
pp. 1598-1602 ◽  
Author(s):  
Thorsten Bach ◽  
Johanna Proessdorf ◽  
Andreas Zech ◽  
Christian Jandl

The first enantioselective total synthesis of (+)-atlanticone C is described. The complex tricyclic protoilludane core was rapidly assembled by a photochemical reaction cascade starting from an easily accessible indanone precursor (3 steps). Optimization of an enantioselective Corey–Bakshi–Shibata reduction permitted a catalytic chiral reso­lution of the racemic photoproduct (45% over two steps; up to 98% ee). The enantiomerically enriched photoproduct was efficiently transformed into the (+)-enantiomer of atlanticone C (10 steps; 18% yield), and the absolute configuration of naturally occurring (–)-atlanticone C was thereby determined.


1962 ◽  
Vol 84 (2) ◽  
pp. 309-310 ◽  
Author(s):  
A. L. Patterson ◽  
Carroll K. Johnson ◽  
Dick. van der Helm ◽  
Jean A. Minkin

2015 ◽  
Vol 56 (38) ◽  
pp. 5306-5308 ◽  
Author(s):  
Kazuo Koike ◽  
Hiroshi Yoshino ◽  
Hong-yu Li ◽  
Tatsunori Sasaki ◽  
Wei Li

1969 ◽  
Vol 23 ◽  
pp. 286-293 ◽  
Author(s):  
Per M. Boll ◽  
Else Sørensen ◽  
Erik Balieu ◽  
Olof Theander ◽  
Alf A. Lindberg ◽  
...  

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