Are reaction rate coefficients additive? Revised transition state theory calculations for OH + alkane reactions

1991 ◽  
Vol 23 (5) ◽  
pp. 397-417 ◽  
Author(s):  
N. Cohen
Keyword(s):  
Transition State ◽  
Transition State Theory ◽  
Reaction Rate ◽  
State Theory ◽  
Rate Coefficients

scholarly journals The Limitation of the Combination of Transition State Theory and Thermodynamics for the Reactions of Proteins and Nucleic Acids

Biomolecules ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 28
Author(s):  
Nobuo Shimamoto
Keyword(s):  
Nucleic Acids ◽  
Transition State ◽  
Stationary State ◽  
Transition State Theory ◽  
Reaction Rate ◽  
State Theory

When a reaction is accompanied by a change with the speed close to or slower than the reaction rate, a circulating reaction flow can exist among the reaction states in the macroscopic stationary state. If the accompanying change were at equilibrium in the timescale of the relevant reaction, the transition-state theory would hold to eliminate the flow.

Sign in / Sign up

Export Citation Format

Share Document