scholarly journals A Natural Rubber Waste Derived Surfactant for High Internal Phase Emulsion Templating of Poly(Dicyclopentadiene)

2021 ◽  
pp. 2100110
Author(s):  
Viktor Schallert ◽  
Christian Slugovc
Keyword(s):  
Natural Rubber ◽  
High Internal Phase Emulsion ◽  
Rubber Waste ◽  
Internal Phase ◽  
Emulsion Templating

scholarly journals A Natural Rubber Waste Derived Surfactant for High Internal Phase Emulsion Templating of Poly(dicyclopentadiene)

2021 ◽  
Author(s):  
Viktor Schallert ◽  
Christian Slugovc
Keyword(s):  
Natural Rubber ◽  
Ring Opening ◽  
Ester Group ◽  
Ionic Surfactants ◽  
Ionic Surfactant ◽  
High Internal Phase Emulsion ◽  
Cross Metathesis ◽  
Rubber Waste ◽  
Internal Phase ◽  
Emulsion Templating

The use of a surfactant derived from the degradation of natural rubber gloves via cross-metathesis with methyl acrylate and subsequent saponification of the ester group for the stabilization of water in dicyclopentadiene high internal phase emulsions is described. The versatility of the resulting high internal phase emulsion was demonstrated by polymerizing the continuous dicyclopentadiene phase via Ring-opening Metathesis Polymerization yielding macroporous poly(dicyclopentadiene) foams with a porosity of 82 %. The use of the ionic surfactant allows for the preparation of foams, which are resistant to absorb water. This property was hitherto not accessible with protocols involving the use of non-ionic surfactants commonly employed in emulsion templating of polymers.<br>

scholarly journals A Natural Rubber Waste Derived Surfactant for High Internal Phase Emulsion Templating of Poly(dicyclopentadiene)

2021 ◽  
Author(s):  
Viktor Schallert ◽  
Christian Slugovc
Keyword(s):  
Natural Rubber ◽  
Ring Opening ◽  
Ester Group ◽  
Ionic Surfactants ◽  
Ionic Surfactant ◽  
High Internal Phase Emulsion ◽  
Cross Metathesis ◽  
Rubber Waste ◽  
Internal Phase ◽  
Emulsion Templating

The use of a surfactant derived from the degradation of natural rubber gloves via cross-metathesis with methyl acrylate and subsequent saponification of the ester group for the stabilization of water in dicyclopentadiene high internal phase emulsions is described. The versatility of the resulting high internal phase emulsion was demonstrated by polymerizing the continuous dicyclopentadiene phase via Ring-opening Metathesis Polymerization yielding macroporous poly(dicyclopentadiene) foams with a porosity of 82 %. The use of the ionic surfactant allows for the preparation of foams, which are resistant to absorb water. This property was hitherto not accessible with protocols involving the use of non-ionic surfactants commonly employed in emulsion templating of polymers.<br>

Engineering bicontinuous polymeric monoliths through high internal phase emulsion templating

2020 ◽  
Vol 22 ◽  
pp. 100813
Author(s):  
Jin-Jin Li ◽  
Yin-Ning Zhou ◽  
Zheng-Hong Luo ◽  
Shiping Zhu
Keyword(s):  
High Internal Phase Emulsion ◽  
Internal Phase ◽  
Emulsion Templating

scholarly journals Macroporous poly(dicyclopentadiene) γFe2O3/Fe3O4 nanocomposite foams by high internal phase emulsion templating

2013 ◽  
Vol 1 (27) ◽  
pp. 7971 ◽  
Author(s):  
Sebastijan Kovačič ◽  
Nadejda B. Matsko ◽  
Gregor Ferk ◽  
Christian Slugovc
Keyword(s):  
High Internal Phase Emulsion ◽  
Nanocomposite Foams ◽  
Internal Phase ◽  
Emulsion Templating

scholarly journals Silk scaffolds achieved using Pickering high internal phase emulsion templating and ionic liquids

RSC Advances ◽  
2013 ◽  
Vol 3 (46) ◽  
pp. 24025 ◽  
Author(s):  
Nolene Byrne ◽  
Rasike DeSilva ◽  
Catherine P. Whitby ◽  
Xungai Wang
Keyword(s):  
Ionic Liquids ◽  
High Internal Phase Emulsion ◽  
Internal Phase ◽  
Silk Scaffolds ◽  
Emulsion Templating

scholarly journals A facile fabrication of porous fluoro-polymer with excellent mechanical properties based on high internal phase emulsion templating using PLA as co-stabilizer

RSC Advances ◽  
2019 ◽  
Vol 9 (69) ◽  
pp. 40513-40522 ◽  
Author(s):  
Yongkang Wang ◽  
Umair Azhar ◽  
Jinxuan He ◽  
Huiying Chen ◽  
Jianzhi Zhao ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
High Internal Phase Emulsion ◽  
Internal Phase ◽  
Facile Fabrication ◽  
The Stability ◽  
Emulsion Templating

Effect of PLA on the stability of fluorinated-HIPE and size tuning of the resultant fluoro-polyHIPE with enhanced mechanical properties.

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