Magnetic field dependence of solvent proton relaxation rates induced by Gd3+ and Mn2+ complexes of various polyaza macrocyclic ligands: Implications for NMR imaging

1986 ◽  
Vol 3 (2) ◽  
pp. 242-250 ◽  
Author(s):  
C. F. G. C. Geraldes ◽  
A. D. Sherry ◽  
R. D. Brown ◽  
S. H. Koenig
1984 ◽  
Vol 1 (4) ◽  
pp. 496-501 ◽  
Author(s):  
Seymour H. Koenig ◽  
Coral Baglin ◽  
Rodney D. Brown ◽  
C. Fred Brewer

1985 ◽  
Vol 2 (2) ◽  
pp. 159-168 ◽  
Author(s):  
Seymour H. Koening ◽  
Rodney D. Brown ◽  
Edward J. Goldstein ◽  
Keith R. Burnett ◽  
Gerald L. Wolf

1993 ◽  
Vol 47 (14) ◽  
pp. 9155-9157 ◽  
Author(s):  
J. A. Martindale ◽  
S. E. Barrett ◽  
K. E. O’Hara ◽  
C. P. Slichter ◽  
W. C. Lee ◽  
...  

2000 ◽  
Vol 651 ◽  
Author(s):  
J.-P. Korb ◽  
A. Van-Quynh ◽  
R. G. Bryant

AbstractThe magnetic field dependence of 1H spin lattice relaxation rates in noncrystalline macromolecular solids including engineering polymers, proteins, and biological tissues is described by a power law, 1/T1 = Aω0-b, where ω0 is the Larmor frequency, A and b are constants. We show that the magnetic field dependence of the proton 1/T1 may be quantitatively related to structural fluctuations along the backbone that modulate proton-proton dipolar couplings. The parameters A and b are related to the dipolar coupling strength, the energy for the highest vibrational frequency in the polymer backbone, and the fractal dimensionality of the proton spatial distribution.


Sign in / Sign up

Export Citation Format

Share Document